Surface interrogation of CoPi water oxidation catalyst by scanning electrochemical microscopy

Hyun S. Ahn, Allen J. Bard

Research output: Contribution to journalArticle

56 Citations (Scopus)

Abstract

Despite exhaustive spectroscopic investigations on the CoPi oxygen-evolving catalyst over the past several years, little is known about the surface cobalt sites and intermediates in direct contact with water that are responsible for the actual catalysis. Many studies thus far have been limited to ex situ characterizations or bulk film measurements, often in the absence of solvent. Here we describe an investigation of the CoPi catalyst by surface interrogation scanning electrochemical microscopy (SI-SECM). This method should allow us to selectively study surface atoms separately from the bulk in a solvent-filled environment. By SI-SECM, independent titrations of surface CoIII and CoIV were performed, yielding a direct measurement of the surface active-site density of a CoPi electrode (11 Co/nm2). The pseudo-first-order reaction rate constants of CoIII and CoIV with water were determined to be 0.19 and >2 s-1, respectively, through time-dependent titration measurements.

Original languageEnglish
Pages (from-to)612-615
Number of pages4
JournalJournal of the American Chemical Society
Volume137
Issue number2
DOIs
Publication statusPublished - 2015 Jan 21

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Electrochemical Scanning Microscopy
Microscopic examination
Scanning
Oxidation
Catalysts
Water
Cobalt
Catalysis
Catalytic Domain
Electrodes
Oxygen
Titration
Reaction rates
Rate constants
Atoms

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

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Surface interrogation of CoPi water oxidation catalyst by scanning electrochemical microscopy. / Ahn, Hyun S.; Bard, Allen J.

In: Journal of the American Chemical Society, Vol. 137, No. 2, 21.01.2015, p. 612-615.

Research output: Contribution to journalArticle

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