Surface Interrogation Scanning Electrochemical Microscopy for a Photoelectrochemical Reaction: Water Oxidation on a Hematite Surface

Jae Young Kim, Hyun S. Ahn, Allen J. Bard

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

To understand the pathway of a photoelectrochemical (PEC) reaction, quantitative knowledge of reaction intermediates is important. We describe here surface interrogation scanning electrochemical microscopy for this purpose (PEC SI-SECM), where a light pulse to a photoactive semiconductor film at a given potential generates intermediates that are then analyzed by a tip generated titrant at known times after the light pulse. The improvements were demonstrated for photoelectrochemical water oxidation (oxygen evolution) reaction on a hematite surface. The density of photoactive sites, proposed to be Fe4+ species, on a hematite surface was successfully quantified, and the photoelectrochemical water oxidation reaction dynamics were elucidated by time-dependent redox titration experiments. The new configuration of PEC SI-SECM should find expanded usage to understand and investigate more complicated PEC reactions with other materials.

Original languageEnglish
Pages (from-to)3045-3049
Number of pages5
JournalAnalytical Chemistry
Volume90
Issue number5
DOIs
Publication statusPublished - 2018 Mar 6

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

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