Surface oxygen vacancy origin of electron accumulation in indium oxide

Research output: Contribution to journalArticlepeer-review

69 Citations (Scopus)

Abstract

Metal oxides are typically insulating materials that can be made conductive through aliovalent doping and/or non-stoichiometry. Recent studies have identified conductive states at surfaces and interfaces of pure oxide materials; high electron concentrations are present, resulting in a high-mobility two-dimensional electron gas. We demonstrate for In2O3 that the energy required to form an oxygen vacancy decreases rapidly towards the (111) surface, where the coordination environment is lowered. This is a general feature of metal oxide systems that can result in a metal-insulator transition where donors are produced at chemically reduced extended defects.

Original languageEnglish
Article number261910
JournalApplied Physics Letters
Volume98
Issue number26
DOIs
Publication statusPublished - 2011 Jun 27

Bibliographical note

Funding Information:
I would like to acknowledge useful discussions with P. D. C. King, C. R. A. Catlow, and A. A. Sokol. Access to the HECToR supercomputer was facilitated through membership of the UK’s HPC Materials Chemistry Consortium, which is funded by EPSRC (Grant No. EP/F067496).

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy (miscellaneous)

Fingerprint

Dive into the research topics of 'Surface oxygen vacancy origin of electron accumulation in indium oxide'. Together they form a unique fingerprint.

Cite this