Syntheses and NMR study of [(2-dimethylaminomethyl)phenyl]vinylsilane derivatives and [(2-dimethylaminomethyl)phenyl]ethylsilane derivatives

Hyeon Mo Cho, Jung Im Jang, Chang Hwan Kim, Sueg Geun Lee, Myong Euy Lee

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4 Citations (Scopus)

Abstract

Various vinylsilanes, SiX(CH=CH2)(CH3) [2-(CH3)2NCH2C6 H4], and ethylsilanes, SiX(CH2CH3) (CH3)[2-(CH3)2NCH2 C6H4] [X=Cl (1); OMe (2); H (3); F (4); OSiMe3 (5); NMe2 (6); Me (7)], were synthesized in order to investigate the electronic effect of vinyl group on silicon atom having an intramolecular coordination arm. The magnitude of Δδ (ethyl→vinyl for 29Si-NMR) of chlorosilane, 1, was the biggest one among 1-7. The differences of 29Si chemical shifts between vinylsilanes and ethylsilanes increased in the following order: X=Me, NMe2<H<OSiMe3<OMe<F<Cl.

Original languageEnglish
Pages (from-to)43-47
Number of pages5
JournalJournal of Organometallic Chemistry
Volume679
Issue number1
DOIs
Publication statusPublished - 2003 Aug 1

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All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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