Syntheses of phosphorylcholine-substituted silsesquioxanes via thiol-ene 'click' reaction

Lei Liu; Su Jung Lee; Myong Euy Lee; Philjae Kang; Moon Gun Choi

doi:10.1016/j.tetlet.2015.02.021

Syntheses of phosphorylcholine-substituted silsesquioxanes via thiol-ene 'click' reaction

Lei Liu, Su Jung Lee, Myong Euy Lee, Philjae Kang, Moon Gun Choi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Phosphorylcholine-substituted silsesquioxanes were synthesized via the UV-initiated thiol-ene 'click' reaction of octakis(3-mercaptopropyl)octasilsesquioxane (POSS-SH) with 2-methacryloyloxyethylphosphorylcholine or allylphosphorylcholine in mixed (DMF/MeOH) solvents, respectively. In addition, the crystal structures of POSS-SH and MPC were first determined.

Original language	English
Pages (from-to)	1562-1565
Number of pages	4
Journal	Tetrahedron Letters
Volume	56
Issue number	12
DOIs	https://doi.org/10.1016/j.tetlet.2015.02.021
Publication status	Published - 2015 Mar 18

Bibliographical note

Funding Information:
This research was supported by the Research and Education Center for Advanced Silicon Materials (RECASM) financially supported by the KCC Corporation . The authors also thank the KCI for providing chemicals.

Publisher Copyright:
© 2015 Elsevier Ltd. All rights reserved.

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2015.02.021

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title = "Syntheses of phosphorylcholine-substituted silsesquioxanes via thiol-ene 'click' reaction",

abstract = "Phosphorylcholine-substituted silsesquioxanes were synthesized via the UV-initiated thiol-ene 'click' reaction of octakis(3-mercaptopropyl)octasilsesquioxane (POSS-SH) with 2-methacryloyloxyethylphosphorylcholine or allylphosphorylcholine in mixed (DMF/MeOH) solvents, respectively. In addition, the crystal structures of POSS-SH and MPC were first determined.",

author = "Lei Liu and Lee, {Su Jung} and Lee, {Myong Euy} and Philjae Kang and Choi, {Moon Gun}",

note = "Funding Information: This research was supported by the Research and Education Center for Advanced Silicon Materials (RECASM) financially supported by the KCC Corporation . The authors also thank the KCI for providing chemicals. Publisher Copyright: {\textcopyright} 2015 Elsevier Ltd. All rights reserved.",

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AU - Liu, Lei

AU - Lee, Su Jung

AU - Lee, Myong Euy

AU - Kang, Philjae

AU - Choi, Moon Gun

N1 - Funding Information: This research was supported by the Research and Education Center for Advanced Silicon Materials (RECASM) financially supported by the KCC Corporation . The authors also thank the KCI for providing chemicals. Publisher Copyright: © 2015 Elsevier Ltd. All rights reserved.

PY - 2015/3/18

Y1 - 2015/3/18

N2 - Phosphorylcholine-substituted silsesquioxanes were synthesized via the UV-initiated thiol-ene 'click' reaction of octakis(3-mercaptopropyl)octasilsesquioxane (POSS-SH) with 2-methacryloyloxyethylphosphorylcholine or allylphosphorylcholine in mixed (DMF/MeOH) solvents, respectively. In addition, the crystal structures of POSS-SH and MPC were first determined.

AB - Phosphorylcholine-substituted silsesquioxanes were synthesized via the UV-initiated thiol-ene 'click' reaction of octakis(3-mercaptopropyl)octasilsesquioxane (POSS-SH) with 2-methacryloyloxyethylphosphorylcholine or allylphosphorylcholine in mixed (DMF/MeOH) solvents, respectively. In addition, the crystal structures of POSS-SH and MPC were first determined.

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Syntheses of phosphorylcholine-substituted silsesquioxanes via thiol-ene 'click' reaction

Abstract

Bibliographical note

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