Synthesis and application of hexagonal perovskite BaNiO3 with quadrivalent nickel under atmospheric and low-temperature conditions

Jin Goo Lee, Ho Jung Hwang, Ohchan Kwon, Ok Sung Jeon, Jeongseok Jang, Yong-Gun Shul

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A hexagonal perovskite BaNiO3 with unusually high-valence nickel(iv) was synthesized under atmospheric and low-temperature conditions by an ethylenediamine-derived wet-chemical route. Secondary phases disappeared with increase in the pH value, and the single-phase BaNiO3 was successfully synthesized at pH 10. The specific surface area was ∼32 m2 g-1, which is significantly enhanced compared to the BaNiO3 (0.3 m2 g-1) synthesized by flux-mediated crystal growth. The BaNiO3 was used as an oxygen-evolution reaction (OER) catalyst, and the specific mass activity was ∼5 times higher than that of the BaNiO3 synthesized by flux-mediated crystal growth. As a result, the ethylenediamine-derived sol-gel synthesis could be a simple technique to prepare crystalline compounds such as perovskites and spinels, with unusually high-valence transition metals.

Original languageEnglish
Pages (from-to)10731-10734
Number of pages4
JournalChemical Communications
Volume52
Issue number71
DOIs
Publication statusPublished - 2016 Jan 1

Fingerprint

ethylenediamine
Crystallization
Nickel
Crystal growth
Perovskite
Fluxes
Specific surface area
Sol-gels
Transition metals
Oxygen
Crystalline materials
Temperature
Catalysts
perovskite

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Lee, Jin Goo ; Hwang, Ho Jung ; Kwon, Ohchan ; Jeon, Ok Sung ; Jang, Jeongseok ; Shul, Yong-Gun. / Synthesis and application of hexagonal perovskite BaNiO3 with quadrivalent nickel under atmospheric and low-temperature conditions. In: Chemical Communications. 2016 ; Vol. 52, No. 71. pp. 10731-10734.
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Synthesis and application of hexagonal perovskite BaNiO3 with quadrivalent nickel under atmospheric and low-temperature conditions. / Lee, Jin Goo; Hwang, Ho Jung; Kwon, Ohchan; Jeon, Ok Sung; Jang, Jeongseok; Shul, Yong-Gun.

In: Chemical Communications, Vol. 52, No. 71, 01.01.2016, p. 10731-10734.

Research output: Contribution to journalArticle

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T1 - Synthesis and application of hexagonal perovskite BaNiO3 with quadrivalent nickel under atmospheric and low-temperature conditions

AU - Lee, Jin Goo

AU - Hwang, Ho Jung

AU - Kwon, Ohchan

AU - Jeon, Ok Sung

AU - Jang, Jeongseok

AU - Shul, Yong-Gun

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AB - A hexagonal perovskite BaNiO3 with unusually high-valence nickel(iv) was synthesized under atmospheric and low-temperature conditions by an ethylenediamine-derived wet-chemical route. Secondary phases disappeared with increase in the pH value, and the single-phase BaNiO3 was successfully synthesized at pH 10. The specific surface area was ∼32 m2 g-1, which is significantly enhanced compared to the BaNiO3 (0.3 m2 g-1) synthesized by flux-mediated crystal growth. The BaNiO3 was used as an oxygen-evolution reaction (OER) catalyst, and the specific mass activity was ∼5 times higher than that of the BaNiO3 synthesized by flux-mediated crystal growth. As a result, the ethylenediamine-derived sol-gel synthesis could be a simple technique to prepare crystalline compounds such as perovskites and spinels, with unusually high-valence transition metals.

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