Mn/Pb and Mn/Ni mixed oxide were prepared at ambient temperature by reduction of KMnO4 with Mn, Pb, and Ni salts. This low-temperature approach provides amorphous structure of the active material. The specific capacitance of pure MnO2 was estimated to be 166 F/g and increased to 210 and 185 F/g for Mn/Ni and Mn/Pb oxides, respectively. The carbon loading was optimized at 20 wt %. Based on a single electrode, the Mn/Ni mixed oxide showed a high rate capability of 3.12 Wh/kg at constant power discharge of 1 kW/kg.
|Journal||Journal of the Electrochemical Society|
|Publication status||Published - 2003 Mar|
All Science Journal Classification (ASJC) codes
- Electronic, Optical and Magnetic Materials
- Renewable Energy, Sustainability and the Environment
- Surfaces, Coatings and Films
- Materials Chemistry