Synthesis and characterization of TiO                         2                         /Ag/polymer ternary nanoparticles via surface-initiated atom transfer radical polymerization

Jung Tae Park; Joo Hwan Koh; Jin Ah Seo; Yong Soo Cho; Jong Hak Kim

doi:10.1016/j.apsusc.2011.01.063

Synthesis and characterization of TiO ₂ /Ag/polymer ternary nanoparticles via surface-initiated atom transfer radical polymerization

Jung Tae Park, Joo Hwan Koh, Jin Ah Seo, Yong Soo Cho, Jong Hak Kim

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

We report on the novel ternary hybrid materials consisting of semiconductor (TiO ₂ ), metal (Ag) and polymer (poly(oxyethylene methacrylate) (POEM)). First, a hydrophilic polymer, i.e. POEM, was grafted from TiO ₂ nanoparticles via the surface-initiated atom transfer radical polymerization (ATRP) technique. These TiO ₂ -POEM brush nanoparticles were used to template the formation of Ag nanoparticles by introduction of a AgCF ₃ SO ₃ precursor and a NaBH ₄ aqueous solution for reduction process. Successful grafting of polymeric chains from the surface of TiO ₂ nanoparticles and the in situ formation of Ag nanoparticles within the polymeric chains were confirmed using transmission electron microscopy (TEM), UV-vis spectroscopy, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). FT-IR spectroscopy also revealed the specific interaction of Ag nanoparticles with the C=O groups of POEM brushes. This study presents a simple route for the in situ synthesis of both metal and polymer confined within the semiconductor, producing ternary hybrid inorganic-organic nanomaterials.

Original language	English
Pages (from-to)	8301-8306
Number of pages	6
Journal	Applied Surface Science
Volume	257
Issue number	20
DOIs	https://doi.org/10.1016/j.apsusc.2011.01.063
Publication status	Published - 2011 Aug 1

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation (NRF) grant funded by the Korea government (MEST) through the Active Polymer Center for Pattern Integration (R11-2007-050-00000-0) and the Korea Center for Artificial Photosynthesis (KCAP) located in Sogang University (NRF-2009-C1AAA001-2009-0093879). This work was also financially supported by the Ministry of Knowledge Economy (MKE) and Korea Institute for Advancement in Technology (KIAT) through the Workforce Development Program in Strategic Technology and the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) (20104010100500).

All Science Journal Classification (ASJC) codes

Chemistry(all)
Condensed Matter Physics
Physics and Astronomy(all)
Surfaces and Interfaces
Surfaces, Coatings and Films

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Park, J. T., Koh, J. H., Seo, J. A., Cho, Y. S., & Kim, J. H. (2011). Synthesis and characterization of TiO ₂ /Ag/polymer ternary nanoparticles via surface-initiated atom transfer radical polymerization Applied Surface Science, 257(20), 8301-8306. https://doi.org/10.1016/j.apsusc.2011.01.063

Park, Jung Tae ; Koh, Joo Hwan ; Seo, Jin Ah ; Cho, Yong Soo ; Kim, Jong Hak. / Synthesis and characterization of TiO ₂ /Ag/polymer ternary nanoparticles via surface-initiated atom transfer radical polymerization In: Applied Surface Science. 2011 ; Vol. 257, No. 20. pp. 8301-8306.

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title = " Synthesis and characterization of TiO 2 /Ag/polymer ternary nanoparticles via surface-initiated atom transfer radical polymerization ",

abstract = " We report on the novel ternary hybrid materials consisting of semiconductor (TiO 2 ), metal (Ag) and polymer (poly(oxyethylene methacrylate) (POEM)). First, a hydrophilic polymer, i.e. POEM, was grafted from TiO 2 nanoparticles via the surface-initiated atom transfer radical polymerization (ATRP) technique. These TiO 2 -POEM brush nanoparticles were used to template the formation of Ag nanoparticles by introduction of a AgCF 3 SO 3 precursor and a NaBH 4 aqueous solution for reduction process. Successful grafting of polymeric chains from the surface of TiO 2 nanoparticles and the in situ formation of Ag nanoparticles within the polymeric chains were confirmed using transmission electron microscopy (TEM), UV-vis spectroscopy, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). FT-IR spectroscopy also revealed the specific interaction of Ag nanoparticles with the C=O groups of POEM brushes. This study presents a simple route for the in situ synthesis of both metal and polymer confined within the semiconductor, producing ternary hybrid inorganic-organic nanomaterials.",

author = "Park, {Jung Tae} and Koh, {Joo Hwan} and Seo, {Jin Ah} and Cho, {Yong Soo} and Kim, {Jong Hak}",

note = "Funding Information: This work was supported by the National Research Foundation (NRF) grant funded by the Korea government (MEST) through the Active Polymer Center for Pattern Integration (R11-2007-050-00000-0) and the Korea Center for Artificial Photosynthesis (KCAP) located in Sogang University (NRF-2009-C1AAA001-2009-0093879). This work was also financially supported by the Ministry of Knowledge Economy (MKE) and Korea Institute for Advancement in Technology (KIAT) through the Workforce Development Program in Strategic Technology and the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) (20104010100500).",

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Park, JT, Koh, JH, Seo, JA, Cho, YS & Kim, JH 2011, ' Synthesis and characterization of TiO ₂ /Ag/polymer ternary nanoparticles via surface-initiated atom transfer radical polymerization ', Applied Surface Science, vol. 257, no. 20, pp. 8301-8306. https://doi.org/10.1016/j.apsusc.2011.01.063

Synthesis and characterization of TiO ₂ /Ag/polymer ternary nanoparticles via surface-initiated atom transfer radical polymerization . / Park, Jung Tae; Koh, Joo Hwan; Seo, Jin Ah; Cho, Yong Soo ; Kim, Jong Hak.

In: Applied Surface Science, Vol. 257, No. 20, 01.08.2011, p. 8301-8306.

Research output: Contribution to journal › Article › peer-review

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AU - Kim, Jong Hak

N1 - Funding Information: This work was supported by the National Research Foundation (NRF) grant funded by the Korea government (MEST) through the Active Polymer Center for Pattern Integration (R11-2007-050-00000-0) and the Korea Center for Artificial Photosynthesis (KCAP) located in Sogang University (NRF-2009-C1AAA001-2009-0093879). This work was also financially supported by the Ministry of Knowledge Economy (MKE) and Korea Institute for Advancement in Technology (KIAT) through the Workforce Development Program in Strategic Technology and the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) (20104010100500).

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N2 - We report on the novel ternary hybrid materials consisting of semiconductor (TiO 2 ), metal (Ag) and polymer (poly(oxyethylene methacrylate) (POEM)). First, a hydrophilic polymer, i.e. POEM, was grafted from TiO 2 nanoparticles via the surface-initiated atom transfer radical polymerization (ATRP) technique. These TiO 2 -POEM brush nanoparticles were used to template the formation of Ag nanoparticles by introduction of a AgCF 3 SO 3 precursor and a NaBH 4 aqueous solution for reduction process. Successful grafting of polymeric chains from the surface of TiO 2 nanoparticles and the in situ formation of Ag nanoparticles within the polymeric chains were confirmed using transmission electron microscopy (TEM), UV-vis spectroscopy, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). FT-IR spectroscopy also revealed the specific interaction of Ag nanoparticles with the C=O groups of POEM brushes. This study presents a simple route for the in situ synthesis of both metal and polymer confined within the semiconductor, producing ternary hybrid inorganic-organic nanomaterials.

AB - We report on the novel ternary hybrid materials consisting of semiconductor (TiO 2 ), metal (Ag) and polymer (poly(oxyethylene methacrylate) (POEM)). First, a hydrophilic polymer, i.e. POEM, was grafted from TiO 2 nanoparticles via the surface-initiated atom transfer radical polymerization (ATRP) technique. These TiO 2 -POEM brush nanoparticles were used to template the formation of Ag nanoparticles by introduction of a AgCF 3 SO 3 precursor and a NaBH 4 aqueous solution for reduction process. Successful grafting of polymeric chains from the surface of TiO 2 nanoparticles and the in situ formation of Ag nanoparticles within the polymeric chains were confirmed using transmission electron microscopy (TEM), UV-vis spectroscopy, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). FT-IR spectroscopy also revealed the specific interaction of Ag nanoparticles with the C=O groups of POEM brushes. This study presents a simple route for the in situ synthesis of both metal and polymer confined within the semiconductor, producing ternary hybrid inorganic-organic nanomaterials.

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