Synthesis and crystal structure of a unique linear homoditopic ligand bifacially complexed to lithium picrate

Leo A. Paquette; Jinsung Tae; Judith C. Gallucci

doi:10.1021/ol9903436

Synthesis and crystal structure of a unique linear homoditopic ligand bifacially complexed to lithium picrate

Leo A. Paquette, Jinsung Tae, Judith C. Gallucci

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Preparation of the first rigid homoditopic tris(tetrahydrofuranyl) ligand with a pair of exotopic binding sites specifically tailored for effective coordination to lithium ions is described. The crystallographically defined structural parameters of the monomeric building block and a 1:2 complex of the dimer with lithium picrate reveal the unique features of these materials.

Original language	English
Pages (from-to)	143-146
Number of pages	4
Journal	Organic Letters
Volume	2
Issue number	2
DOIs	https://doi.org/10.1021/ol9903436
Publication status	Published - 2000 Jan 27

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol9903436

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abstract = "Preparation of the first rigid homoditopic tris(tetrahydrofuranyl) ligand with a pair of exotopic binding sites specifically tailored for effective coordination to lithium ions is described. The crystallographically defined structural parameters of the monomeric building block and a 1:2 complex of the dimer with lithium picrate reveal the unique features of these materials.",

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