Synthesis and crystal structure of as-synthesized and calcined pure silica zeolite ITQ-12

Xiaobo Yang, Miguel A. Camblor, Yongjae Lee, Haiming Liu, David H. Olson

Research output: Contribution to journalArticle

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Abstract

The small-pore pure silica zeolite ITQ-12 has been synthesized with fumed silica as the silica source in the presence of 1,3,4-trimethylimidazolium hydroxide and hydrofluoric acid under hydrothermal conditions at 448 K. Rietveld refinement using synchrotron X-ray diffraction data of the calcined ITQ-12 product taken at 298 K confirms the proposed topology, framework type code ITW, which can be described by a monoclinic unit cell [Si24O48] having Cm symmetry. Unit cell parameters are a = 10.3360(4), b = 15.0177(6), and c = 8.8639(4) Å, β = 105.356(3) Å3. For as-synthesized ITQ-12, the occluded fluoride anion is located inside the double four-membered ring, while the flat 1,3,4-trimethylimidazolium cation lies on the equatorial plane of the slit-shaped [44546 484] cage, with its longest dimension in the [010] direction. The monoclinic unit cell |[(C6N2H 11)+2F-2|[Si 24O48], having Cm symmetry, has parameters a = 10.4478(3), b = 14.9854(4), and c = 8.8366(3) Å, β = 105.935(2)°, and cell volume V= 1330.34(7) Å3 at 298 K. Cooperative structure-directing effects during the crystallization of ITQ-12 are discussed in terms of the structure of the as-made material.

Original languageEnglish
Pages (from-to)10403-10409
Number of pages7
JournalJournal of the American Chemical Society
Volume126
Issue number33
DOIs
Publication statusPublished - 2004 Aug 25

Fingerprint

Zeolites
Silicon Dioxide
Crystal structure
Silica
Hydrofluoric Acid
Hydrofluoric acid
Synchrotrons
Rietveld refinement
Crystallization
Least-Squares Analysis
Fluorides
Cell Size
X-Ray Diffraction
Anions
Cations
Negative ions
Positive ions
Topology
X ray diffraction

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Yang, Xiaobo ; Camblor, Miguel A. ; Lee, Yongjae ; Liu, Haiming ; Olson, David H. / Synthesis and crystal structure of as-synthesized and calcined pure silica zeolite ITQ-12. In: Journal of the American Chemical Society. 2004 ; Vol. 126, No. 33. pp. 10403-10409.
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abstract = "The small-pore pure silica zeolite ITQ-12 has been synthesized with fumed silica as the silica source in the presence of 1,3,4-trimethylimidazolium hydroxide and hydrofluoric acid under hydrothermal conditions at 448 K. Rietveld refinement using synchrotron X-ray diffraction data of the calcined ITQ-12 product taken at 298 K confirms the proposed topology, framework type code ITW, which can be described by a monoclinic unit cell [Si24O48] having Cm symmetry. Unit cell parameters are a = 10.3360(4), b = 15.0177(6), and c = 8.8639(4) {\AA}, β = 105.356(3) {\AA}3. For as-synthesized ITQ-12, the occluded fluoride anion is located inside the double four-membered ring, while the flat 1,3,4-trimethylimidazolium cation lies on the equatorial plane of the slit-shaped [44546 484] cage, with its longest dimension in the [010] direction. The monoclinic unit cell |[(C6N2H 11)+2F-2|[Si 24O48], having Cm symmetry, has parameters a = 10.4478(3), b = 14.9854(4), and c = 8.8366(3) {\AA}, β = 105.935(2)°, and cell volume V= 1330.34(7) {\AA}3 at 298 K. Cooperative structure-directing effects during the crystallization of ITQ-12 are discussed in terms of the structure of the as-made material.",
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Synthesis and crystal structure of as-synthesized and calcined pure silica zeolite ITQ-12. / Yang, Xiaobo; Camblor, Miguel A.; Lee, Yongjae; Liu, Haiming; Olson, David H.

In: Journal of the American Chemical Society, Vol. 126, No. 33, 25.08.2004, p. 10403-10409.

Research output: Contribution to journalArticle

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T1 - Synthesis and crystal structure of as-synthesized and calcined pure silica zeolite ITQ-12

AU - Yang, Xiaobo

AU - Camblor, Miguel A.

AU - Lee, Yongjae

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AU - Olson, David H.

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N2 - The small-pore pure silica zeolite ITQ-12 has been synthesized with fumed silica as the silica source in the presence of 1,3,4-trimethylimidazolium hydroxide and hydrofluoric acid under hydrothermal conditions at 448 K. Rietveld refinement using synchrotron X-ray diffraction data of the calcined ITQ-12 product taken at 298 K confirms the proposed topology, framework type code ITW, which can be described by a monoclinic unit cell [Si24O48] having Cm symmetry. Unit cell parameters are a = 10.3360(4), b = 15.0177(6), and c = 8.8639(4) Å, β = 105.356(3) Å3. For as-synthesized ITQ-12, the occluded fluoride anion is located inside the double four-membered ring, while the flat 1,3,4-trimethylimidazolium cation lies on the equatorial plane of the slit-shaped [44546 484] cage, with its longest dimension in the [010] direction. The monoclinic unit cell |[(C6N2H 11)+2F-2|[Si 24O48], having Cm symmetry, has parameters a = 10.4478(3), b = 14.9854(4), and c = 8.8366(3) Å, β = 105.935(2)°, and cell volume V= 1330.34(7) Å3 at 298 K. Cooperative structure-directing effects during the crystallization of ITQ-12 are discussed in terms of the structure of the as-made material.

AB - The small-pore pure silica zeolite ITQ-12 has been synthesized with fumed silica as the silica source in the presence of 1,3,4-trimethylimidazolium hydroxide and hydrofluoric acid under hydrothermal conditions at 448 K. Rietveld refinement using synchrotron X-ray diffraction data of the calcined ITQ-12 product taken at 298 K confirms the proposed topology, framework type code ITW, which can be described by a monoclinic unit cell [Si24O48] having Cm symmetry. Unit cell parameters are a = 10.3360(4), b = 15.0177(6), and c = 8.8639(4) Å, β = 105.356(3) Å3. For as-synthesized ITQ-12, the occluded fluoride anion is located inside the double four-membered ring, while the flat 1,3,4-trimethylimidazolium cation lies on the equatorial plane of the slit-shaped [44546 484] cage, with its longest dimension in the [010] direction. The monoclinic unit cell |[(C6N2H 11)+2F-2|[Si 24O48], having Cm symmetry, has parameters a = 10.4478(3), b = 14.9854(4), and c = 8.8366(3) Å, β = 105.935(2)°, and cell volume V= 1330.34(7) Å3 at 298 K. Cooperative structure-directing effects during the crystallization of ITQ-12 are discussed in terms of the structure of the as-made material.

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