Synthesis and Mesomorphic Properties of Palladium (II) Complexes Based on 3,4,5-Trialkoxy Benzonitrile Ligands

Myongsoo Lee, Yong Sik Yoo, Moon-Gun Choi

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The synthesis and characterization of the nitrile ligands 3,4,5-tridodecyloxy benzonitrile (7) and 3,4,5-trioctadecyloxy bezonitrile (8), and their corresponding palladium(II) complexes are described. The nitrile ligands display only a crystalline phase and do not show liquid crystalline behavior, while their corresponding palladium(II) complexes display an enantiotropic columnar mesophase. The induction of the columnar mesophase is mainly due to dimerization through the palladium complexation of the half disk-like nitrile ligands giving rise to a trans square planar geometry.

Original languageEnglish
Pages (from-to)1067-1070
Number of pages4
JournalBulletin of the Korean Chemical Society
Volume18
Issue number10
Publication statusPublished - 1997 Dec 1

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Nitriles
Palladium
Ligands
Crystalline materials
Dimerization
Complexation
Geometry
Liquids
benzonitrile

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

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title = "Synthesis and Mesomorphic Properties of Palladium (II) Complexes Based on 3,4,5-Trialkoxy Benzonitrile Ligands",
abstract = "The synthesis and characterization of the nitrile ligands 3,4,5-tridodecyloxy benzonitrile (7) and 3,4,5-trioctadecyloxy bezonitrile (8), and their corresponding palladium(II) complexes are described. The nitrile ligands display only a crystalline phase and do not show liquid crystalline behavior, while their corresponding palladium(II) complexes display an enantiotropic columnar mesophase. The induction of the columnar mesophase is mainly due to dimerization through the palladium complexation of the half disk-like nitrile ligands giving rise to a trans square planar geometry.",
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Synthesis and Mesomorphic Properties of Palladium (II) Complexes Based on 3,4,5-Trialkoxy Benzonitrile Ligands. / Lee, Myongsoo; Yoo, Yong Sik; Choi, Moon-Gun.

In: Bulletin of the Korean Chemical Society, Vol. 18, No. 10, 01.12.1997, p. 1067-1070.

Research output: Contribution to journalArticle

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AB - The synthesis and characterization of the nitrile ligands 3,4,5-tridodecyloxy benzonitrile (7) and 3,4,5-trioctadecyloxy bezonitrile (8), and their corresponding palladium(II) complexes are described. The nitrile ligands display only a crystalline phase and do not show liquid crystalline behavior, while their corresponding palladium(II) complexes display an enantiotropic columnar mesophase. The induction of the columnar mesophase is mainly due to dimerization through the palladium complexation of the half disk-like nitrile ligands giving rise to a trans square planar geometry.

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