Synthesis and properties of poly(1,1-diethynyl-1-silacyclopent-3-enes and -1-silacyclobutane)

Eun Joo Kim, Jung Woo Park, Yong Rok Kim, Young Tae Park

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Polycarbosilanes containing diacetylene and organosilacyclic groups, such as poly(1,1-diethynyl-1-silacyclopent-3-ene), poly(1,1-diethynyl-3-triethylsilyl-1-silacyclopent-3-ene), and poly(1,1-diethynyl-1-silacyclobutane), were synthesized by the Glaser oxidative coupling polymerization reactions of 1,1-diethynyl-1-silacyclopent-3-ene, 1,1-diethynyl-3-triethylsilyl-1-silacyclopent-3-ene, and 1,1-diethynyl-1-silacyclobutane, respectively. These materials are almost insoluble in usual organic solvents such as CHCl3 and THF. The polymers were characterized by using several spectroscopic methods in solid state. FTIR spectra of all the polymeric materials show that the characteristic C≡C stretching frequencies appear at 2146-2170 cm-1, in particular. The polymers in the solid state show that the strong maximum excitation peaks appear at 255-257 nm and the strong maximum fluorescence emission bands at 401-402 nm. About 71-87% of the initial polymer weights remain at 400°C in nitrogen according to thermogravimetric analysis.

Original languageEnglish
Pages (from-to)484-488
Number of pages5
JournalBulletin of the Korean Chemical Society
Volume24
Issue number4
DOIs
Publication statusPublished - 2003 Apr 20

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Polymers
Organic solvents
Stretching
Thermogravimetric analysis
Nitrogen
Fluorescence
Polymerization

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

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title = "Synthesis and properties of poly(1,1-diethynyl-1-silacyclopent-3-enes and -1-silacyclobutane)",
abstract = "Polycarbosilanes containing diacetylene and organosilacyclic groups, such as poly(1,1-diethynyl-1-silacyclopent-3-ene), poly(1,1-diethynyl-3-triethylsilyl-1-silacyclopent-3-ene), and poly(1,1-diethynyl-1-silacyclobutane), were synthesized by the Glaser oxidative coupling polymerization reactions of 1,1-diethynyl-1-silacyclopent-3-ene, 1,1-diethynyl-3-triethylsilyl-1-silacyclopent-3-ene, and 1,1-diethynyl-1-silacyclobutane, respectively. These materials are almost insoluble in usual organic solvents such as CHCl3 and THF. The polymers were characterized by using several spectroscopic methods in solid state. FTIR spectra of all the polymeric materials show that the characteristic C≡C stretching frequencies appear at 2146-2170 cm-1, in particular. The polymers in the solid state show that the strong maximum excitation peaks appear at 255-257 nm and the strong maximum fluorescence emission bands at 401-402 nm. About 71-87{\%} of the initial polymer weights remain at 400°C in nitrogen according to thermogravimetric analysis.",
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Synthesis and properties of poly(1,1-diethynyl-1-silacyclopent-3-enes and -1-silacyclobutane). / Kim, Eun Joo; Park, Jung Woo; Kim, Yong Rok; Park, Young Tae.

In: Bulletin of the Korean Chemical Society, Vol. 24, No. 4, 20.04.2003, p. 484-488.

Research output: Contribution to journalArticle

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AB - Polycarbosilanes containing diacetylene and organosilacyclic groups, such as poly(1,1-diethynyl-1-silacyclopent-3-ene), poly(1,1-diethynyl-3-triethylsilyl-1-silacyclopent-3-ene), and poly(1,1-diethynyl-1-silacyclobutane), were synthesized by the Glaser oxidative coupling polymerization reactions of 1,1-diethynyl-1-silacyclopent-3-ene, 1,1-diethynyl-3-triethylsilyl-1-silacyclopent-3-ene, and 1,1-diethynyl-1-silacyclobutane, respectively. These materials are almost insoluble in usual organic solvents such as CHCl3 and THF. The polymers were characterized by using several spectroscopic methods in solid state. FTIR spectra of all the polymeric materials show that the characteristic C≡C stretching frequencies appear at 2146-2170 cm-1, in particular. The polymers in the solid state show that the strong maximum excitation peaks appear at 255-257 nm and the strong maximum fluorescence emission bands at 401-402 nm. About 71-87% of the initial polymer weights remain at 400°C in nitrogen according to thermogravimetric analysis.

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