Synthesis, morphology, characterisation, and ethanol gas sensing of hierarchical flower-like Co-doped WO3 nanoplates by solvothermal route

Jong Chan Lim, Changhyun Jin, Myung Sik Choi, Min Young Kim, Sang il Kim, Soon Mok Choi, Seung Hyub Baek, Kyu Hyoung Lee, Hyun Sik Kim

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Three-dimensional flower-like tungsten oxide nanoplates sequentially doped with Co at different concentrations were fabricated using a single solvothermal process. The response of the nanostructure of the n-type tungsten oxide used for sensing ethanol gas, which is a reducing gas, changed sequentially according to the process temperature and doping concentration of Co. This response cannot be attributed to a single reason, but it can be regarded as a result of the combination of several complicated direct and indirect phenomena such as (1) point, line, and cross-section defects on the surface, (2) change in initial resistance corresponding to doping concentration, (3) catalytic effect of dopant, and (4) difference in energy level at heterojunctions. Therefore, unlike in the case of other gas sensing methods that depend on a main cause or mechanism, it might be meaningful in the case of ethanol gas sensing to analyse each cause and predict the results of different combinations.

Original languageEnglish
JournalCeramics International
DOIs
Publication statusAccepted/In press - 2021

Bibliographical note

Funding Information:
This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education ( NRF-2020R1I1A1A01067825 and NRF-2019R1A6A1A11055660 ). This work was also supported by Yonsei-KIST Convergence Research Program . M.S. Choi was supported by the Korea Initiative for fostering University of Research and Innovation (KIURI) Program of the National Research Foundation (NRF) funded by the Korean government (MSIT) ( NRF-2020M3H1A1077207 ).

Publisher Copyright:
© 2021 Elsevier Ltd and Techna Group S.r.l.

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Process Chemistry and Technology
  • Surfaces, Coatings and Films
  • Materials Chemistry

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