Synthesis of a new diamine and its effect on the residual stress of colorless polyimide

Juheon Lee, Kwangin Kim, Gunhwi Kim, Haksoo Han

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A new diamine was designed and synthesized to improve the flexibility of colorless polyimides by reducing residual stress. Four variations of colorless polyimides with the same dianhydride (4,4′-(hexafluoroisopropylidene)-diphthalic) and four different diamines (bis[4-(3-aminophenoxy)-phenyl] sulfone, bis(3-aminophenyl) sulfone, 2,2′-bis(trifluoromethyl)benzidine, and 2,2-bis(4-aminophenyl)-hexafluoropropane) were used. A series of colorless polyimides were prepared by adding the new diamine. The carbon and ether bonds between the benzene rings of the new diamine affected the flexibility and optical properties of colorless polyimide. The synthesis of the new diamine was confirmed by NMR measurements. Furthermore, the decrease in residual stress at room temperature and the glass transition temperature was confirmed. The effect of the new diamine was most evident for polyimide with a bulky and rigid structure. Though a slight yellow color appears because of the broken charge transfer complex balance, controlling the content of the new diamine will allow application of polyimides in flexible display.

Original languageEnglish
Pages (from-to)777-783
Number of pages7
JournalKorean Journal of Chemical Engineering
Volume35
Issue number3
DOIs
Publication statusPublished - 2018 Mar 1

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Diamines
Polyimides
Residual stresses
Sulfones
Flexible displays
Rigid structures
Benzene
Ether
Charge transfer
Ethers
Carbon
Optical properties
Nuclear magnetic resonance
Color

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

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abstract = "A new diamine was designed and synthesized to improve the flexibility of colorless polyimides by reducing residual stress. Four variations of colorless polyimides with the same dianhydride (4,4′-(hexafluoroisopropylidene)-diphthalic) and four different diamines (bis[4-(3-aminophenoxy)-phenyl] sulfone, bis(3-aminophenyl) sulfone, 2,2′-bis(trifluoromethyl)benzidine, and 2,2-bis(4-aminophenyl)-hexafluoropropane) were used. A series of colorless polyimides were prepared by adding the new diamine. The carbon and ether bonds between the benzene rings of the new diamine affected the flexibility and optical properties of colorless polyimide. The synthesis of the new diamine was confirmed by NMR measurements. Furthermore, the decrease in residual stress at room temperature and the glass transition temperature was confirmed. The effect of the new diamine was most evident for polyimide with a bulky and rigid structure. Though a slight yellow color appears because of the broken charge transfer complex balance, controlling the content of the new diamine will allow application of polyimides in flexible display.",
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Synthesis of a new diamine and its effect on the residual stress of colorless polyimide. / Lee, Juheon; Kim, Kwangin; Kim, Gunhwi; Han, Haksoo.

In: Korean Journal of Chemical Engineering, Vol. 35, No. 3, 01.03.2018, p. 777-783.

Research output: Contribution to journalArticle

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