Synthesis of a polyacrylonitrile/tetrachloro-1,4-benzoquinone gel polymer electrolyte for high-performance Li-air batteries

Young Bok Kim, Il To Kim, Myeong Jun Song, Moo Whan Shin

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Gel polymer electrolyte (GPE) is recently attracting a significant attention for lithium air batteries (LABs) due to better reliability compared with liquid type electrolyte and higher ionic conductivity compared with solid type electrolyte. In this paper, we report a new combination of polyacrylonitrile (PAN)-based GPE with tetrachloro-1,4-benzoquinone (tCl-pBQ) as the redox mediator for the LAB application. The synthesized PAN/tCl-pBQ GPE with lithium bis (tri-fluoro-methane-sulfonyl)imide (LiTFSI)/tetraethylene glycol dimethyl ether (TEGDME) displays a decrease in the LAB charge voltage from ~ 4.2 to 3.6 V and a ~ 10% increase in energy cycle efficiency compared with PAN GPE without tCl-pBQ. The decrease in charge voltage improves the cyclability from 8 to 98 cycles. Structural analyses reveal that addition of tCl-pBQ accelerates the formation of an amorphous phase in the PAN-based gel polymer electrolyte matrix, improving the ionic conductivity from 7.64 to 12.5 mS cm−1 at room temperature.

Original languageEnglish
Pages (from-to)835-842
Number of pages8
JournalJournal of Membrane Science
Volume563
DOIs
Publication statusPublished - 2018 Oct 1

Fingerprint

Chloranil
polyacrylonitrile
Polyacrylonitriles
quinones
Electrolytes
electric batteries
Polymers
Gels
Air
electrolytes
gels
Lithium
air
polymers
synthesis
lithium
Ionic conductivity
ion currents
Imides
cycles

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Filtration and Separation

Cite this

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title = "Synthesis of a polyacrylonitrile/tetrachloro-1,4-benzoquinone gel polymer electrolyte for high-performance Li-air batteries",
abstract = "Gel polymer electrolyte (GPE) is recently attracting a significant attention for lithium air batteries (LABs) due to better reliability compared with liquid type electrolyte and higher ionic conductivity compared with solid type electrolyte. In this paper, we report a new combination of polyacrylonitrile (PAN)-based GPE with tetrachloro-1,4-benzoquinone (tCl-pBQ) as the redox mediator for the LAB application. The synthesized PAN/tCl-pBQ GPE with lithium bis (tri-fluoro-methane-sulfonyl)imide (LiTFSI)/tetraethylene glycol dimethyl ether (TEGDME) displays a decrease in the LAB charge voltage from ~ 4.2 to 3.6 V and a ~ 10{\%} increase in energy cycle efficiency compared with PAN GPE without tCl-pBQ. The decrease in charge voltage improves the cyclability from 8 to 98 cycles. Structural analyses reveal that addition of tCl-pBQ accelerates the formation of an amorphous phase in the PAN-based gel polymer electrolyte matrix, improving the ionic conductivity from 7.64 to 12.5 mS cm−1 at room temperature.",
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Synthesis of a polyacrylonitrile/tetrachloro-1,4-benzoquinone gel polymer electrolyte for high-performance Li-air batteries. / Kim, Young Bok; Kim, Il To; Song, Myeong Jun; Shin, Moo Whan.

In: Journal of Membrane Science, Vol. 563, 01.10.2018, p. 835-842.

Research output: Contribution to journalArticle

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AB - Gel polymer electrolyte (GPE) is recently attracting a significant attention for lithium air batteries (LABs) due to better reliability compared with liquid type electrolyte and higher ionic conductivity compared with solid type electrolyte. In this paper, we report a new combination of polyacrylonitrile (PAN)-based GPE with tetrachloro-1,4-benzoquinone (tCl-pBQ) as the redox mediator for the LAB application. The synthesized PAN/tCl-pBQ GPE with lithium bis (tri-fluoro-methane-sulfonyl)imide (LiTFSI)/tetraethylene glycol dimethyl ether (TEGDME) displays a decrease in the LAB charge voltage from ~ 4.2 to 3.6 V and a ~ 10% increase in energy cycle efficiency compared with PAN GPE without tCl-pBQ. The decrease in charge voltage improves the cyclability from 8 to 98 cycles. Structural analyses reveal that addition of tCl-pBQ accelerates the formation of an amorphous phase in the PAN-based gel polymer electrolyte matrix, improving the ionic conductivity from 7.64 to 12.5 mS cm−1 at room temperature.

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