Synthesis of aliphatic ketones from allylic alcohols through consecutive isomerization and chelation-assisted hydroacylation by a rhodium catalyst

Dae Yon Lee, Choong Woon Moon, Chul Ho Jun

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

Abstract: An allylic alcohol, utilized as a precursor for an aliphatic aldehyde, reacted with olefins to afford aliphatic ketones in the presence of RhCl(PPh3)3, 2-amino-4-picoline, aniline, and benzoic acid through a tandem reaction of an isomerization and a chelation-assisted hydroacylation.

Original languageEnglish
Pages (from-to)3945-3948
Number of pages4
JournalJournal of Organic Chemistry
Volume67
Issue number11
DOIs
Publication statusPublished - 2002 May 31

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this