Synthesis of aliphatic ketones from allylic alcohols through consecutive isomerization and chelation-assisted hydroacylation by a rhodium catalyst

Dae Yon Lee, Choong Woon Moon, Chul Ho Jun

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

Abstract: An allylic alcohol, utilized as a precursor for an aliphatic aldehyde, reacted with olefins to afford aliphatic ketones in the presence of RhCl(PPh3)3, 2-amino-4-picoline, aniline, and benzoic acid through a tandem reaction of an isomerization and a chelation-assisted hydroacylation.

Original languageEnglish
Pages (from-to)3945-3948
Number of pages4
JournalJournal of Organic Chemistry
Volume67
Issue number11
DOIs
Publication statusPublished - 2002 May 31

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Rhodium
Benzoic Acid
Alkenes
Isomerization
Chelation
Ketones
Aldehydes
Catalysts
chlorotris(triphenylphosphine)rhodium
aniline
allyl alcohol
2-amino-4-picoline

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

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Synthesis of aliphatic ketones from allylic alcohols through consecutive isomerization and chelation-assisted hydroacylation by a rhodium catalyst. / Lee, Dae Yon; Moon, Choong Woon; Jun, Chul Ho.

In: Journal of Organic Chemistry, Vol. 67, No. 11, 31.05.2002, p. 3945-3948.

Research output: Contribution to journalArticle

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AU - Jun, Chul Ho

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N2 - Abstract: An allylic alcohol, utilized as a precursor for an aliphatic aldehyde, reacted with olefins to afford aliphatic ketones in the presence of RhCl(PPh3)3, 2-amino-4-picoline, aniline, and benzoic acid through a tandem reaction of an isomerization and a chelation-assisted hydroacylation.

AB - Abstract: An allylic alcohol, utilized as a precursor for an aliphatic aldehyde, reacted with olefins to afford aliphatic ketones in the presence of RhCl(PPh3)3, 2-amino-4-picoline, aniline, and benzoic acid through a tandem reaction of an isomerization and a chelation-assisted hydroacylation.

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