Synthesis of cobalt cluster-based supramolecular triple-stranded helicates

Hyojong Yoo, Jeonghee Lee, Philjae Kang, Moon Gun Choi

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13 Citations (Scopus)

Abstract

A cobalt cluster-based triple-stranded helicate, Co8(PDA)6(PTA)3(DMF)3(H2O)3 (1) (PDA = 2,6-pyridinedicarboxylate, PTA = benzene-1,3-dicarboxylate, DMF = dimethylformamide) was successfully synthesized and fully characterized. Complex 1 can be used as a supramolecular building block in constructing a higher-order helix-of-helix structure, [Co8(PDA)6(PTA)3(DMF)2(H2O)4-0.51(Co(OHn)2)] (n = 1 or 2) (2).

Original languageEnglish
Pages (from-to)14213-14216
Number of pages4
JournalDalton Transactions
Volume44
Issue number32
DOIs
Publication statusPublished - 2015 Aug 28

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All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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