Synthesis of cycloalkanones from dienes and allylamines through C-H and C-C bond activation catalyzed by a rhodium(I) complex

Dae Yon Lee, In Jung Kim, Chul Ho Jun

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

Formaldehyde in disguise: The allylic amine 1 is used as a masked form of formaldehyde in the rhodium-catalyzed cyclization of dienes 2. The reaction provides access to various cycloalkanones 3 through chelation-assisted C-H- and C-C-bond activation.

Original languageEnglish
Pages (from-to)3031-3033
Number of pages3
JournalAngewandte Chemie - International Edition
Volume41
Issue number16
DOIs
Publication statusPublished - 2002 Aug 16

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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