Synthesis of cycloalkanones from dienes and allylamines through C-H and C-C bond activation catalyzed by a rhodium(I) complex

Dae Yon Lee, In Jung Kim, Chul-Ho Jun

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

Formaldehyde in disguise: The allylic amine 1 is used as a masked form of formaldehyde in the rhodium-catalyzed cyclization of dienes 2. The reaction provides access to various cycloalkanones 3 through chelation-assisted C-H- and C-C-bond activation.

Original languageEnglish
Pages (from-to)3031-3033
Number of pages3
JournalAngewandte Chemie - International Edition
Volume41
Issue number16
DOIs
Publication statusPublished - 2002 Aug 16

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Allylamine
Rhodium
Formaldehyde
Chemical activation
Cyclization
Chelation
Amines

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

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abstract = "Formaldehyde in disguise: The allylic amine 1 is used as a masked form of formaldehyde in the rhodium-catalyzed cyclization of dienes 2. The reaction provides access to various cycloalkanones 3 through chelation-assisted C-H- and C-C-bond activation.",
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Synthesis of cycloalkanones from dienes and allylamines through C-H and C-C bond activation catalyzed by a rhodium(I) complex. / Lee, Dae Yon; Kim, In Jung; Jun, Chul-Ho.

In: Angewandte Chemie - International Edition, Vol. 41, No. 16, 16.08.2002, p. 3031-3033.

Research output: Contribution to journalArticle

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T1 - Synthesis of cycloalkanones from dienes and allylamines through C-H and C-C bond activation catalyzed by a rhodium(I) complex

AU - Lee, Dae Yon

AU - Kim, In Jung

AU - Jun, Chul-Ho

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AB - Formaldehyde in disguise: The allylic amine 1 is used as a masked form of formaldehyde in the rhodium-catalyzed cyclization of dienes 2. The reaction provides access to various cycloalkanones 3 through chelation-assisted C-H- and C-C-bond activation.

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