Synthesis of cycloalkanones from dienes and allylamines through C-H and C-C bond activation catalyzed by a rhodium(I) complex

Dae Yon Lee; In Jung Kim; Chul Ho Jun

doi:10.1002/1521-3773(20020816)41:16<3031::AID-ANIE3031>3.0.CO;2-X

Synthesis of cycloalkanones from dienes and allylamines through C-H and C-C bond activation catalyzed by a rhodium(I) complex

Dae Yon Lee, In Jung Kim, Chul Ho Jun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

Formaldehyde in disguise: The allylic amine 1 is used as a masked form of formaldehyde in the rhodium-catalyzed cyclization of dienes 2. The reaction provides access to various cycloalkanones 3 through chelation-assisted C-H- and C-C-bond activation.

Original language	English
Pages (from-to)	3031-3033
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	16
DOIs	https://doi.org/10.1002/1521-3773(20020816)41:16<3031::AID-ANIE3031>3.0.CO;2-X
Publication status	Published - 2002 Aug 16

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/1521-3773(20020816)41:16<3031::AID-ANIE3031>3.0.CO;2-X

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abstract = "Formaldehyde in disguise: The allylic amine 1 is used as a masked form of formaldehyde in the rhodium-catalyzed cyclization of dienes 2. The reaction provides access to various cycloalkanones 3 through chelation-assisted C-H- and C-C-bond activation.",

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Synthesis of cycloalkanones from dienes and allylamines through C-H and C-C bond activation catalyzed by a rhodium(I) complex

Abstract

All Science Journal Classification (ASJC) codes

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