Synthesis of Jatropha Curcas biodiesel and physicochemical investigation of molecular interactions in Jatropha Curcas biodiesel + C2-C 3-alkanol blends

Satish Kumar, Wonsub Lim, Vinod Kumar Sharma, Sunil Kumar Garg, Il Moon

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The physicochemical properties such as densities and speeds of sound have been measured for Jatropha Curcas biodiesel (1) + ethan-1-ol or propan-1-ol (2) binary mixtures over entire composition range at T = (288.15 to 308.15) K and atmospheric pressure. The measured data have been utilized to determine excess molar volumes V12E, isentropic compressibilities (κS)12, and deviations in isentropic compressibilities (ΔκS)12. The V 12E and (ΔκS)12 values were fitted to Redlich-Kister polynomial equation to calculate the adjustable parameters together with their standard deviations. The measured data and derived physical properties have been discussed in terms of the dipole-dipole, dipole induced-dipole interactions, and hydrogen bonding between fatty acid methyl esters (biodiesel) and ethan-1-ol or propan-1-ol molecules and their structural factors.

Original languageEnglish
Pages (from-to)55-61
Number of pages7
JournalJournal of Molecular Liquids
Volume181
DOIs
Publication statusPublished - 2013 May 1

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Spectroscopy
  • Physical and Theoretical Chemistry
  • Materials Chemistry

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