Synthesis of novel mesoporous material through intercalation of anionic silicates into cationic charged layered material hydrotalcite

M. H. Kim, S. H. Jang, I. M. Kang, Yun Goo Song, J. J. Lee, J. S. Hong, M. Lee

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

The new porous materials (Si-HTlc) were successfully synthesized by the intercalation reaction of anionic silicates into hydrotalcite (HTlc) under mild temperature, conditional pH and anionic silicate concentration. The as-prepared Si-HTlcs display slit-like pore structure with 12.3-17.0 nm pore size and a surface area of 370-650 m2 g-1 with the creation of some micropores but mainly of mesopores. The main evidences and factors about the results are also discussed. Furthermore, these facts suggest the formation of new pore framework through a strong interaction of silicate anions into the HTlc inner-surface with the interlayer hydroxyl groups.

Original languageEnglish
Title of host publicationFrom Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference
PublisherElsevier Inc.
Pages1963-1968
Number of pages6
EditionB
ISBN (Print)0444530681, 9780444530684
DOIs
Publication statusPublished - 2007 Jan 1

Publication series

NameStudies in Surface Science and Catalysis
NumberB
Volume170
ISSN (Print)0167-2991

Fingerprint

hydrotalcite
Silicates
Mesoporous materials
Intercalation
intercalation
silicates
porosity
synthesis
porous materials
Pore structure
Hydroxyl Radical
Pore size
Anions
slits
Porous materials
interlayers
Negative ions
anions

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Kim, M. H., Jang, S. H., Kang, I. M., Song, Y. G., Lee, J. J., Hong, J. S., & Lee, M. (2007). Synthesis of novel mesoporous material through intercalation of anionic silicates into cationic charged layered material hydrotalcite. In From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference (B ed., pp. 1963-1968). (Studies in Surface Science and Catalysis; Vol. 170, No. B). Elsevier Inc.. https://doi.org/10.1016/S0167-2991(07)81086-X
Kim, M. H. ; Jang, S. H. ; Kang, I. M. ; Song, Yun Goo ; Lee, J. J. ; Hong, J. S. ; Lee, M. / Synthesis of novel mesoporous material through intercalation of anionic silicates into cationic charged layered material hydrotalcite. From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference. B. ed. Elsevier Inc., 2007. pp. 1963-1968 (Studies in Surface Science and Catalysis; B).
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Kim, MH, Jang, SH, Kang, IM, Song, YG, Lee, JJ, Hong, JS & Lee, M 2007, Synthesis of novel mesoporous material through intercalation of anionic silicates into cationic charged layered material hydrotalcite. in From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference. B edn, Studies in Surface Science and Catalysis, no. B, vol. 170, Elsevier Inc., pp. 1963-1968. https://doi.org/10.1016/S0167-2991(07)81086-X

Synthesis of novel mesoporous material through intercalation of anionic silicates into cationic charged layered material hydrotalcite. / Kim, M. H.; Jang, S. H.; Kang, I. M.; Song, Yun Goo; Lee, J. J.; Hong, J. S.; Lee, M.

From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference. B. ed. Elsevier Inc., 2007. p. 1963-1968 (Studies in Surface Science and Catalysis; Vol. 170, No. B).

Research output: Chapter in Book/Report/Conference proceedingChapter

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AB - The new porous materials (Si-HTlc) were successfully synthesized by the intercalation reaction of anionic silicates into hydrotalcite (HTlc) under mild temperature, conditional pH and anionic silicate concentration. The as-prepared Si-HTlcs display slit-like pore structure with 12.3-17.0 nm pore size and a surface area of 370-650 m2 g-1 with the creation of some micropores but mainly of mesopores. The main evidences and factors about the results are also discussed. Furthermore, these facts suggest the formation of new pore framework through a strong interaction of silicate anions into the HTlc inner-surface with the interlayer hydroxyl groups.

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Kim MH, Jang SH, Kang IM, Song YG, Lee JJ, Hong JS et al. Synthesis of novel mesoporous material through intercalation of anionic silicates into cationic charged layered material hydrotalcite. In From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference. B ed. Elsevier Inc. 2007. p. 1963-1968. (Studies in Surface Science and Catalysis; B). https://doi.org/10.1016/S0167-2991(07)81086-X