Synthesis of Poly(methyl methacrylate-co-butyl acrylate)/Perfluorosilyl methacrylate core-shell nanoparticles

Novel approach for optimization of coating process

Jun Won Kook, Yongsoo Kim, Kiseob Hwang, Jung-Hyun Kim, Jun Young Lee

Research output: Contribution to journalArticle

Abstract

In this study, the coating order of two monomers in the shell polymerization process of core-shell nanoparticles was altered to facilitate easy coating and optimize the properties of the coated surface to simplify the additional coating formulation process. To obtain a glass transition temperature suitable for coating, a core was synthesized by the copolymerization of an acryl monomer. A perfluoro monomer and silane monomer were additionally added to synthesize nanoparticles exhibiting both water-oil repellency and anchoring properties. In order to realize various surface properties, the nanoparticles underwent surface modification and cellulose fiber was introduced. Through the various data described in this text, the surface properties improved with the order of the introduction of the two monomers.

Original languageEnglish
Article number1186
JournalPolymers
Volume10
Issue number11
DOIs
Publication statusPublished - 2018 Oct 24

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Methacrylates
Polymethyl Methacrylate
Polymethyl methacrylates
Monomers
Nanoparticles
Coatings
Surface properties
Silanes
Cellulose
Copolymerization
Surface treatment
Oils
Polymerization
n-butyl acrylate
Water
Fibers

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Polymers and Plastics

Cite this

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title = "Synthesis of Poly(methyl methacrylate-co-butyl acrylate)/Perfluorosilyl methacrylate core-shell nanoparticles: Novel approach for optimization of coating process",
abstract = "In this study, the coating order of two monomers in the shell polymerization process of core-shell nanoparticles was altered to facilitate easy coating and optimize the properties of the coated surface to simplify the additional coating formulation process. To obtain a glass transition temperature suitable for coating, a core was synthesized by the copolymerization of an acryl monomer. A perfluoro monomer and silane monomer were additionally added to synthesize nanoparticles exhibiting both water-oil repellency and anchoring properties. In order to realize various surface properties, the nanoparticles underwent surface modification and cellulose fiber was introduced. Through the various data described in this text, the surface properties improved with the order of the introduction of the two monomers.",
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Synthesis of Poly(methyl methacrylate-co-butyl acrylate)/Perfluorosilyl methacrylate core-shell nanoparticles : Novel approach for optimization of coating process. / Kook, Jun Won; Kim, Yongsoo; Hwang, Kiseob; Kim, Jung-Hyun; Lee, Jun Young.

In: Polymers, Vol. 10, No. 11, 1186, 24.10.2018.

Research output: Contribution to journalArticle

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T1 - Synthesis of Poly(methyl methacrylate-co-butyl acrylate)/Perfluorosilyl methacrylate core-shell nanoparticles

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AU - Kook, Jun Won

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AU - Lee, Jun Young

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