Synthesis of poly(vinyl chloride)-g-poly(ionic liquid) and its application to tuning surface for copper nanoparticles

Je Hyun Oh; Won Seok Chi; Jung Hyun Lee; Jong Hak Kim; Sang Wook Kang

doi:10.1021/ie400787w

Synthesis of poly(vinyl chloride)-g-poly(ionic liquid) and its application to tuning surface for copper nanoparticles

Je Hyun Oh, Won Seok Chi, Jung Hyun Lee, Jong Hak Kim, Sang Wook Kang

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

We successfully synthesized PVC-g-P([Ebim][Tf₂N]) by utilizing atom-transfer radical polymerization (ATRP) for the preparation of polymer/Cu nanocomposite. When Cu flakes were stirred in PVC-g-P([Ebim][Tf₂N]) without any additives, Cu nanoparticles were stably generated to form the polymer/Cu nanocomposite. The dissociation of nanoparticles from the flakes is attributable to the strong interaction between cations of PVC-g-P([Ebim][Tf ₂N]) and the metal surface. The generated Cu nanoparticles exhibited a polydisperse distribution, as confirmed by UV-vis spectral analysis and transmission electron microscopy (TEM) imaging. Furthermore, the surface state of the Cu nanoparticles was investigated by X-ray photoelectron spectroscopy (XPS), which was confirmed by a decrease in binding energy.

Original language	English
Pages (from-to)	9607-9611
Number of pages	5
Journal	Industrial and Engineering Chemistry Research
Volume	52
Issue number	28
DOIs	https://doi.org/10.1021/ie400787w
Publication status	Published - 2013 Jul 17

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)
Industrial and Manufacturing Engineering

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10.1021/ie400787w

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title = "Synthesis of poly(vinyl chloride)-g-poly(ionic liquid) and its application to tuning surface for copper nanoparticles",

abstract = "We successfully synthesized PVC-g-P([Ebim][Tf2N]) by utilizing atom-transfer radical polymerization (ATRP) for the preparation of polymer/Cu nanocomposite. When Cu flakes were stirred in PVC-g-P([Ebim][Tf2N]) without any additives, Cu nanoparticles were stably generated to form the polymer/Cu nanocomposite. The dissociation of nanoparticles from the flakes is attributable to the strong interaction between cations of PVC-g-P([Ebim][Tf 2N]) and the metal surface. The generated Cu nanoparticles exhibited a polydisperse distribution, as confirmed by UV-vis spectral analysis and transmission electron microscopy (TEM) imaging. Furthermore, the surface state of the Cu nanoparticles was investigated by X-ray photoelectron spectroscopy (XPS), which was confirmed by a decrease in binding energy.",

author = "Oh, {Je Hyun} and Chi, {Won Seok} and Lee, {Jung Hyun} and Kim, {Jong Hak} and Kang, {Sang Wook}",

year = "2013",

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doi = "10.1021/ie400787w",

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journal = "Industrial and Engineering Chemistry Research",

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T1 - Synthesis of poly(vinyl chloride)-g-poly(ionic liquid) and its application to tuning surface for copper nanoparticles

AU - Oh, Je Hyun

AU - Chi, Won Seok

AU - Lee, Jung Hyun

AU - Kim, Jong Hak

AU - Kang, Sang Wook

PY - 2013/7/17

Y1 - 2013/7/17

N2 - We successfully synthesized PVC-g-P([Ebim][Tf2N]) by utilizing atom-transfer radical polymerization (ATRP) for the preparation of polymer/Cu nanocomposite. When Cu flakes were stirred in PVC-g-P([Ebim][Tf2N]) without any additives, Cu nanoparticles were stably generated to form the polymer/Cu nanocomposite. The dissociation of nanoparticles from the flakes is attributable to the strong interaction between cations of PVC-g-P([Ebim][Tf 2N]) and the metal surface. The generated Cu nanoparticles exhibited a polydisperse distribution, as confirmed by UV-vis spectral analysis and transmission electron microscopy (TEM) imaging. Furthermore, the surface state of the Cu nanoparticles was investigated by X-ray photoelectron spectroscopy (XPS), which was confirmed by a decrease in binding energy.

AB - We successfully synthesized PVC-g-P([Ebim][Tf2N]) by utilizing atom-transfer radical polymerization (ATRP) for the preparation of polymer/Cu nanocomposite. When Cu flakes were stirred in PVC-g-P([Ebim][Tf2N]) without any additives, Cu nanoparticles were stably generated to form the polymer/Cu nanocomposite. The dissociation of nanoparticles from the flakes is attributable to the strong interaction between cations of PVC-g-P([Ebim][Tf 2N]) and the metal surface. The generated Cu nanoparticles exhibited a polydisperse distribution, as confirmed by UV-vis spectral analysis and transmission electron microscopy (TEM) imaging. Furthermore, the surface state of the Cu nanoparticles was investigated by X-ray photoelectron spectroscopy (XPS), which was confirmed by a decrease in binding energy.

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Synthesis of poly(vinyl chloride)-g-poly(ionic liquid) and its application to tuning surface for copper nanoparticles

Abstract

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