Synthesis of thermally stable porous SiC hollow spheres and control of the shell thickness

Seong Cheol Noh, Seung Young Lee, Sungrye Kim, Sungho Yoon, Yong-Gun Shul, Kwang Deog Jung

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Thermally stable SiC hollow spheres were prepared using SiO2 templates with two layers. At the calcination at higher than 1300 °C, the SiC hollow sphere could be obtained. The shell thickness of the porous SiC hollow spheres can be controlled by the molar ratio of TMS/TEOS. The pore volumes and BET surface areas of the template SiO2 increased with the molar ratio of TMS/TEOS, while those of the SiC/SiO2 and SiC spheres decreased. It is evident that the pore sizes of the SiC hollow spheres were not influenced by the TMS/TEOS ratio. The wall thickness of the SiC sample increased with an increase in the TMS/TEOS mole ratio. The prepared SiC hollow spheres with the surface area higher than 770 m2/g were thermally stable up to temperatures higher than 700°C.

Original languageEnglish
Pages (from-to)11-17
Number of pages7
JournalMicroporous and Mesoporous Materials
Volume199
DOIs
Publication statusPublished - 2014 Nov 15

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hollow
synthesis
templates
porosity
Calcination
roasting
Pore size
Temperature

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials

Cite this

Noh, Seong Cheol ; Lee, Seung Young ; Kim, Sungrye ; Yoon, Sungho ; Shul, Yong-Gun ; Jung, Kwang Deog. / Synthesis of thermally stable porous SiC hollow spheres and control of the shell thickness. In: Microporous and Mesoporous Materials. 2014 ; Vol. 199. pp. 11-17.
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Synthesis of thermally stable porous SiC hollow spheres and control of the shell thickness. / Noh, Seong Cheol; Lee, Seung Young; Kim, Sungrye; Yoon, Sungho; Shul, Yong-Gun; Jung, Kwang Deog.

In: Microporous and Mesoporous Materials, Vol. 199, 15.11.2014, p. 11-17.

Research output: Contribution to journalArticle

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T1 - Synthesis of thermally stable porous SiC hollow spheres and control of the shell thickness

AU - Noh, Seong Cheol

AU - Lee, Seung Young

AU - Kim, Sungrye

AU - Yoon, Sungho

AU - Shul, Yong-Gun

AU - Jung, Kwang Deog

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AB - Thermally stable SiC hollow spheres were prepared using SiO2 templates with two layers. At the calcination at higher than 1300 °C, the SiC hollow sphere could be obtained. The shell thickness of the porous SiC hollow spheres can be controlled by the molar ratio of TMS/TEOS. The pore volumes and BET surface areas of the template SiO2 increased with the molar ratio of TMS/TEOS, while those of the SiC/SiO2 and SiC spheres decreased. It is evident that the pore sizes of the SiC hollow spheres were not influenced by the TMS/TEOS ratio. The wall thickness of the SiC sample increased with an increase in the TMS/TEOS mole ratio. The prepared SiC hollow spheres with the surface area higher than 770 m2/g were thermally stable up to temperatures higher than 700°C.

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