Templated formation of silver nanoparticles using amphiphilic poly(epichlorohydrine-g-styrene) film

Jung Tae Park, Joo Hwan Koh, Jin Ah Seo, Dong Kyu Roh, Jong Hak Kim

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

This work has demonstrated that a novel amphiphilic poly(epichlorohydrine)- graft-polystyrene (PECH-g-PS) copolymer at 34:66 wt% was synthesized via atom transfer radical polymerization (ATRP) of styrene using PECH as a macroinitiator. The structure of the graft copolymer was characterized by nuclear magnetic resonance (1H NMR) and FTIR spectroscopy, demonstrating that the "grafting from" method using ATRP was successful. The self-assembled graft copolymer was used as a template film for the in-situ growth of silver nanoparticles from AgCF3SO3 precursor under UV irradiation. The in situ formation of silver nanoparticles with 6-8 nm in average size in the solid state template film was confirmed by transmission electron microscopy (TEM), UV-visible spectroscopy and wide angle X-ray scattering (WAXS). Differential scanning calorimetry (DSC) also displayed the selective . incorporation and the in situ formation of silver nanoparticles within the hydrophilic PECH domains, probably due to stronger interaction of the silvers with the ether oxygens of PECH backbone than that with hydrophobic PS side chains.

Original languageEnglish
Pages (from-to)301-306
Number of pages6
JournalMacromolecular Research
Volume17
Issue number5
DOIs
Publication statusPublished - 2009 May

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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