Abstract
Amphiphilic comb-like copolymer consisting of a poly(vinyl chloride) (PVC) backbone and poly(styrene sulfonic acid) (PSSA) side chains, i.e. PVC-g-PSSA at 68:32 wt.% was synthesized via atom transfer radical polymerization (ATRP). This self-assembled graft copolymer film was used to template the growth of Ag-Au bimetallic nanoparticles in the solid state by introducing NaBH4 as a reducing agent. The in situ formation of Ag-Au bimetallic nanoparticles in the graft copolymer film was confirmed by UV-visible spectroscopy, X-ray diffraction (XRD) and transmission electron microscopy (TEM). High resolution TEM picture showed the formation of spherical Ag-Au core-shell nanoparticles. To the best of our knowledge, this is the first report on the solid-state synthesis of Ag-Au bimetallic core-shell nanoparticles using amphiphilic comb-like copolymer film.
| Original language | English |
|---|---|
| Pages (from-to) | 4492-4493 |
| Number of pages | 2 |
| Journal | Materials Letters |
| Volume | 62 |
| Issue number | 30 |
| DOIs | |
| Publication status | Published - 2008 Dec 15 |
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All Science Journal Classification (ASJC) codes
- Materials Science(all)
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering
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Templated synthesis of Ag-Au bimetallic nanoparticles by amphiphilic PVC-g-PSSA graft copolymer film. / Seo, Jin Ah; Park, Jung Tae; Koh, Joo Hwan; Kim, Jong Hak.
In: Materials Letters, Vol. 62, No. 30, 15.12.2008, p. 4492-4493.Research output: Contribution to journal › Article
TY - JOUR
T1 - Templated synthesis of Ag-Au bimetallic nanoparticles by amphiphilic PVC-g-PSSA graft copolymer film
AU - Seo, Jin Ah
AU - Park, Jung Tae
AU - Koh, Joo Hwan
AU - Kim, Jong Hak
PY - 2008/12/15
Y1 - 2008/12/15
N2 - Amphiphilic comb-like copolymer consisting of a poly(vinyl chloride) (PVC) backbone and poly(styrene sulfonic acid) (PSSA) side chains, i.e. PVC-g-PSSA at 68:32 wt.% was synthesized via atom transfer radical polymerization (ATRP). This self-assembled graft copolymer film was used to template the growth of Ag-Au bimetallic nanoparticles in the solid state by introducing NaBH4 as a reducing agent. The in situ formation of Ag-Au bimetallic nanoparticles in the graft copolymer film was confirmed by UV-visible spectroscopy, X-ray diffraction (XRD) and transmission electron microscopy (TEM). High resolution TEM picture showed the formation of spherical Ag-Au core-shell nanoparticles. To the best of our knowledge, this is the first report on the solid-state synthesis of Ag-Au bimetallic core-shell nanoparticles using amphiphilic comb-like copolymer film.
AB - Amphiphilic comb-like copolymer consisting of a poly(vinyl chloride) (PVC) backbone and poly(styrene sulfonic acid) (PSSA) side chains, i.e. PVC-g-PSSA at 68:32 wt.% was synthesized via atom transfer radical polymerization (ATRP). This self-assembled graft copolymer film was used to template the growth of Ag-Au bimetallic nanoparticles in the solid state by introducing NaBH4 as a reducing agent. The in situ formation of Ag-Au bimetallic nanoparticles in the graft copolymer film was confirmed by UV-visible spectroscopy, X-ray diffraction (XRD) and transmission electron microscopy (TEM). High resolution TEM picture showed the formation of spherical Ag-Au core-shell nanoparticles. To the best of our knowledge, this is the first report on the solid-state synthesis of Ag-Au bimetallic core-shell nanoparticles using amphiphilic comb-like copolymer film.
UR - http://www.scopus.com/inward/record.url?scp=53049096539&partnerID=8YFLogxK
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U2 - 10.1016/j.matlet.2008.08.006
DO - 10.1016/j.matlet.2008.08.006
M3 - Article
AN - SCOPUS:53049096539
VL - 62
SP - 4492
EP - 4493
JO - Materials Letters
JF - Materials Letters
SN - 0167-577X
IS - 30
ER -