Templated synthesis of mesoporous aluminas by graft copolymer and their CO2 adsorption capacities

Harim Jeon, Sung Hoon Ahn, Jong Hak Kim, Yoon Jae Min, Ki Bong Lee

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Abstract

Mesoporous aluminas were synthesized via a sol-gel process by templating an amphiphilic graft copolymer, PVC-g-POEM, consisting of a poly(vinyl chloride) (PVC) backbone and poly(oxyethylene methacrylate) (POEM) side chains. The mesoporous structures of aluminas with large surface areas were confirmed by X-ray diffraction, transmission electron microscopy, and nitrogen adsorption/desorption analysis. Aluminas synthesized with PVC-g-POEM graft copolymer exhibited higher CO2 adsorption capacities (0.7 mol CO 2/kg sorbent) than aluminas synthesized without graft copolymer (0.6 mol CO2/kg sorbent). The adsorption capacity of alumina strongly depends on its structure and calcination temperature; amorphous (400 °C) > γ phase (800 °C) > α phase (1000 °C).

Original languageEnglish
Pages (from-to)4020-4025
Number of pages6
JournalJournal of Materials Science
Volume46
Issue number11
DOIs
Publication statusPublished - 2011 Jun 1

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All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

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