Ternary cobalt spinel oxides for solar driven hydrogen production

Theory and experiment

Aron Walsh, Kwang Soon Ahn, Sudhakar Shet, Muhammad N. Huda, Todd G. Deutsch, Heli Wang, John A. Turner, Su Huai Wei, Yanfa Yan, Mowafak M. Al-Jassim

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

Discovery of a chemically stable, light absorbing and low resistivity metal oxide with band edges aligned to the water redox potentials has been a goal of physical scientists for the past forty years. Despite an immense amount of effort, no solution has been uncovered. We present a combined theoretical and experimental exploration of a series of unconventional ternary cobalt spinel oxides, which offer chemical functionality through substitution on the octahedral spinel B site. First-principles predictions of the substitution of group 13 cations (Al, Ga, In) in Co 3 O 4 to form a series of homologous CoX 2 O 4 spinel compounds are combined with experimental synthesis and photoelectrochemical characterization. Ultimately, while tunable band gaps in the visible range can be obtained, the material performance is limited by poor carrier transport properties associated with small polaron carriers. Future design pathways for metal oxide exploration are discussed.

Original languageEnglish
Pages (from-to)774-782
Number of pages9
JournalEnergy and Environmental Science
Volume2
Issue number7
DOIs
Publication statusPublished - 2009 Oct 1

Fingerprint

Hydrogen production
Cobalt
cobalt
spinel
Oxides
oxide
hydrogen
substitution
Substitution reactions
Metals
Gene Conversion
Carrier transport
experiment
Experiments
redox potential
Transport properties
Cations
electrical resistivity
Energy gap
cation

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Pollution

Cite this

Walsh, A., Ahn, K. S., Shet, S., Huda, M. N., Deutsch, T. G., Wang, H., ... Al-Jassim, M. M. (2009). Ternary cobalt spinel oxides for solar driven hydrogen production: Theory and experiment. Energy and Environmental Science, 2(7), 774-782. https://doi.org/10.1039/b822903a
Walsh, Aron ; Ahn, Kwang Soon ; Shet, Sudhakar ; Huda, Muhammad N. ; Deutsch, Todd G. ; Wang, Heli ; Turner, John A. ; Wei, Su Huai ; Yan, Yanfa ; Al-Jassim, Mowafak M. / Ternary cobalt spinel oxides for solar driven hydrogen production : Theory and experiment. In: Energy and Environmental Science. 2009 ; Vol. 2, No. 7. pp. 774-782.
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Walsh, A, Ahn, KS, Shet, S, Huda, MN, Deutsch, TG, Wang, H, Turner, JA, Wei, SH, Yan, Y & Al-Jassim, MM 2009, 'Ternary cobalt spinel oxides for solar driven hydrogen production: Theory and experiment', Energy and Environmental Science, vol. 2, no. 7, pp. 774-782. https://doi.org/10.1039/b822903a

Ternary cobalt spinel oxides for solar driven hydrogen production : Theory and experiment. / Walsh, Aron; Ahn, Kwang Soon; Shet, Sudhakar; Huda, Muhammad N.; Deutsch, Todd G.; Wang, Heli; Turner, John A.; Wei, Su Huai; Yan, Yanfa; Al-Jassim, Mowafak M.

In: Energy and Environmental Science, Vol. 2, No. 7, 01.10.2009, p. 774-782.

Research output: Contribution to journalArticle

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