The effect of Ca substitution on the structural and electrical properties of La0.7Sr0.3-xCaxMnO3 perovskite manganite films

Sun Gyu Choi, Hong Sub Lee, Hyejung Choi, Sung Woong Chung, Hyung Ho Park

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3 Citations (Scopus)


This study demonstrates the effect of a Ca substituent for Sr on the structural, chemical, and electrical properties in La0.7Sr 0.3-xCaxMnO3 perovskite manganite films. The structural modification of films was found to be affected by the amount of Ca substituent. Raman spectroscopy analysis reveals a decrease of bond angle and an increase of Jahn-Teller type distortion in MnO6 octahedra with increasing Ca. The resistance value of high resistance state, switching voltage and resistive switching ratio of La0.7Sr0.3-xCa xMnO3 films decreased with increasing amounts of Ca substituent. The relationships among structural, interfacial, and electrical properties including resistive switching behaviour of La0.7Sr 0.3-xCaxMnO3 were examined.

Original languageEnglish
Article number425102
JournalJournal of Physics D: Applied Physics
Issue number42
Publication statusPublished - 2013 Oct 23

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Acoustics and Ultrasonics
  • Surfaces, Coatings and Films


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