The effect of pyridine modification of ni-dobdc on co2 capture under humid conditions

Youn Sang Bae; Jian Liu; Christopher E. Wilmer; Hahnbi Sun; Allison N. Dickey; Min Bum Kim; Annabelle I. Benin; Richard R. Willis; Dushyant Barpaga; M. Douglas LeVan; Randall Q. Snurr

doi:10.1039/c3cc44954h

The effect of pyridine modification of ni-dobdc on co₂ capture under humid conditions

Youn Sang Bae, Jian Liu, Christopher E. Wilmer, Hahnbi Sun, Allison N. Dickey, Min Bum Kim, Annabelle I. Benin, Richard R. Willis, Dushyant Barpaga, M. Douglas LeVan, Randall Q. Snurr

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

The metal-organic framework Ni-DOBDC was modified with pyridine molecules to make the normally hydrophilic internal surface more hydrophobic. Experiments and molecular simulations show that the pyridine modification reduces H₂O adsorption while retaining substantial CO₂ capacity under the conditions of interest for carbon capture from flue gas.

Original language	English
Pages (from-to)	3296-3298
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	25
DOIs	https://doi.org/10.1039/c3cc44954h
Publication status	Published - 2014 Feb 27

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "The effect of pyridine modification of ni-dobdc on co2 capture under humid conditions",

abstract = "The metal-organic framework Ni-DOBDC was modified with pyridine molecules to make the normally hydrophilic internal surface more hydrophobic. Experiments and molecular simulations show that the pyridine modification reduces H2O adsorption while retaining substantial CO2 capacity under the conditions of interest for carbon capture from flue gas.",

author = "Bae, {Youn Sang} and Jian Liu and Wilmer, {Christopher E.} and Hahnbi Sun and Dickey, {Allison N.} and Kim, {Min Bum} and Benin, {Annabelle I.} and Willis, {Richard R.} and Dushyant Barpaga and LeVan, {M. Douglas} and Snurr, {Randall Q.}",

year = "2014",

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doi = "10.1039/c3cc44954h",

language = "English",

volume = "50",

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journal = "Chemical Communications",

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T1 - The effect of pyridine modification of ni-dobdc on co2 capture under humid conditions

AU - Bae, Youn Sang

AU - Liu, Jian

AU - Wilmer, Christopher E.

AU - Sun, Hahnbi

AU - Dickey, Allison N.

AU - Kim, Min Bum

AU - Benin, Annabelle I.

AU - Willis, Richard R.

AU - Barpaga, Dushyant

AU - LeVan, M. Douglas

AU - Snurr, Randall Q.

PY - 2014/2/27

Y1 - 2014/2/27

N2 - The metal-organic framework Ni-DOBDC was modified with pyridine molecules to make the normally hydrophilic internal surface more hydrophobic. Experiments and molecular simulations show that the pyridine modification reduces H2O adsorption while retaining substantial CO2 capacity under the conditions of interest for carbon capture from flue gas.

AB - The metal-organic framework Ni-DOBDC was modified with pyridine molecules to make the normally hydrophilic internal surface more hydrophobic. Experiments and molecular simulations show that the pyridine modification reduces H2O adsorption while retaining substantial CO2 capacity under the conditions of interest for carbon capture from flue gas.

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DO - 10.1039/c3cc44954h

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EP - 3298

JO - Chemical Communications

JF - Chemical Communications

IS - 25

ER -

The effect of pyridine modification of ni-dobdc on co₂ capture under humid conditions

Abstract

All Science Journal Classification (ASJC) codes

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