The effect of varying solvents for MoS2 treatment on its catalytic efficiencies for HER and ORR

Xing Juan Chua, Martin Pumera

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

MoS2 has been investigated intensively in the field of catalysis for the hydrogen evolution reaction (HER) in particular. Much effort has been made by various research teams worldwide to look into the specific catalyst design such as nano-structuring, defect engineering or hybrid structures. But what evades us is the fundamental preparation method for the dispersion of powdered MoS2. Individual research teams with their best practices might be subjective and not validated by extensive experimental results. In this report, we find that the overpotential for the catalysis of HER varies from 0.57 to 0.72 V (freshly prepared) when different dispersion media are used, such as acetonitrile, N,N-dimethylformamide, ethanol, methanol and water. In terms of oxygen reduction reaction (ORR) catalysis, less significant differences were found. With both HER and ORR pertinent to the fuel cell industry, this report would serve as an insight to readers when comparing the results of MoS2 catalysis across the literature from different research groups when different solvents were used as the dispersion medium.

Original languageEnglish
Pages (from-to)6610-6619
Number of pages10
JournalPhysical Chemistry Chemical Physics
Volume19
Issue number9
DOIs
Publication statusPublished - 2017 Jan 1

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Catalysis
Hydrogen
catalysis
Oxygen
oxygen
hydrogen
Dimethylformamide
hybrid structures
Methanol
Fuel cells
readers
Ethanol
fuel cells
acetonitrile
ethyl alcohol
methyl alcohol
Defects
Catalysts
industries
Water

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

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The effect of varying solvents for MoS2 treatment on its catalytic efficiencies for HER and ORR. / Chua, Xing Juan; Pumera, Martin.

In: Physical Chemistry Chemical Physics, Vol. 19, No. 9, 01.01.2017, p. 6610-6619.

Research output: Contribution to journalArticle

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