The first porphyrin-subphthalocyaninatoboron(III)-fused hybrid with unique conformation and intramolecular charge transfer behavior

Yuehong Zhang; Juwon Oh; Kang Wang; Dongju Shin; Xiaopeng Zhan; Yingting Zheng; Dongho Kim; Jianzhuang Jiang

doi:10.1039/c6cc05383a

The first porphyrin-subphthalocyaninatoboron(III)-fused hybrid with unique conformation and intramolecular charge transfer behavior

Yuehong Zhang, Juwon Oh, Kang Wang, Dongju Shin, Xiaopeng Zhan, Yingting Zheng, Dongho Kim, Jianzhuang Jiang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Porphyrin and subphthalocyaninatoboron(iii) chromophores have been fused through a quinoxaline moiety, resulting in the first porphyrin-subphthalocyaninatoboron(iii)-fused hybrid with intramolecular charge transfer from tetrapyrrole/tripyrrole chromophores to the quinoxaline moiety. The unique plane-bowl molecular structure of this hybrid was revealed based on single crystal X-ray diffraction analysis for the first time.

Original language	English
Pages (from-to)	10517-10520
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	69
DOIs	https://doi.org/10.1039/c6cc05383a
Publication status	Published - 2016 Sep 7

Bibliographical note

Funding Information:
Financial support for work at the University of Science and Technology Beijing was from the National Key Basic Research Programof China (Grant No. 2013CB933402), the Natural Science Foundation of China (No. 21290174 and 21401009), and the Beijing Municipal Commission of Education. The work at Yonsei University was financially supported by the Global Research Laboratory Program (2013K1A1A2A02050183).

Publisher Copyright:
© 2016 The Royal Society of Chemistry.

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c6cc05383a

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title = "The first porphyrin-subphthalocyaninatoboron(III)-fused hybrid with unique conformation and intramolecular charge transfer behavior",

abstract = "Porphyrin and subphthalocyaninatoboron(iii) chromophores have been fused through a quinoxaline moiety, resulting in the first porphyrin-subphthalocyaninatoboron(iii)-fused hybrid with intramolecular charge transfer from tetrapyrrole/tripyrrole chromophores to the quinoxaline moiety. The unique plane-bowl molecular structure of this hybrid was revealed based on single crystal X-ray diffraction analysis for the first time.",

author = "Yuehong Zhang and Juwon Oh and Kang Wang and Dongju Shin and Xiaopeng Zhan and Yingting Zheng and Dongho Kim and Jianzhuang Jiang",

note = "Funding Information: Financial support for work at the University of Science and Technology Beijing was from the National Key Basic Research Programof China (Grant No. 2013CB933402), the Natural Science Foundation of China (No. 21290174 and 21401009), and the Beijing Municipal Commission of Education. The work at Yonsei University was financially supported by the Global Research Laboratory Program (2013K1A1A2A02050183). Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

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doi = "10.1039/c6cc05383a",

language = "English",

volume = "52",

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journal = "Chemical Communications",

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The first porphyrin-subphthalocyaninatoboron(III)-fused hybrid with unique conformation and intramolecular charge transfer behavior. / Zhang, Yuehong; Oh, Juwon; Wang, Kang; Shin, Dongju; Zhan, Xiaopeng; Zheng, Yingting; Kim, Dongho; Jiang, Jianzhuang.

In: Chemical Communications, Vol. 52, No. 69, 07.09.2016, p. 10517-10520.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The first porphyrin-subphthalocyaninatoboron(III)-fused hybrid with unique conformation and intramolecular charge transfer behavior

AU - Zhang, Yuehong

AU - Oh, Juwon

AU - Wang, Kang

AU - Shin, Dongju

AU - Zhan, Xiaopeng

AU - Zheng, Yingting

AU - Kim, Dongho

AU - Jiang, Jianzhuang

N1 - Funding Information: Financial support for work at the University of Science and Technology Beijing was from the National Key Basic Research Programof China (Grant No. 2013CB933402), the Natural Science Foundation of China (No. 21290174 and 21401009), and the Beijing Municipal Commission of Education. The work at Yonsei University was financially supported by the Global Research Laboratory Program (2013K1A1A2A02050183). Publisher Copyright: © 2016 The Royal Society of Chemistry.

PY - 2016/9/7

Y1 - 2016/9/7

N2 - Porphyrin and subphthalocyaninatoboron(iii) chromophores have been fused through a quinoxaline moiety, resulting in the first porphyrin-subphthalocyaninatoboron(iii)-fused hybrid with intramolecular charge transfer from tetrapyrrole/tripyrrole chromophores to the quinoxaline moiety. The unique plane-bowl molecular structure of this hybrid was revealed based on single crystal X-ray diffraction analysis for the first time.

AB - Porphyrin and subphthalocyaninatoboron(iii) chromophores have been fused through a quinoxaline moiety, resulting in the first porphyrin-subphthalocyaninatoboron(iii)-fused hybrid with intramolecular charge transfer from tetrapyrrole/tripyrrole chromophores to the quinoxaline moiety. The unique plane-bowl molecular structure of this hybrid was revealed based on single crystal X-ray diffraction analysis for the first time.

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The first porphyrin-subphthalocyaninatoboron(III)-fused hybrid with unique conformation and intramolecular charge transfer behavior

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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