Porphyrin and subphthalocyaninatoboron(iii) chromophores have been fused through a quinoxaline moiety, resulting in the first porphyrin-subphthalocyaninatoboron(iii)-fused hybrid with intramolecular charge transfer from tetrapyrrole/tripyrrole chromophores to the quinoxaline moiety. The unique plane-bowl molecular structure of this hybrid was revealed based on single crystal X-ray diffraction analysis for the first time.
Bibliographical noteFunding Information:
Financial support for work at the University of Science and Technology Beijing was from the National Key Basic Research Programof China (Grant No. 2013CB933402), the Natural Science Foundation of China (No. 21290174 and 21401009), and the Beijing Municipal Commission of Education. The work at Yonsei University was financially supported by the Global Research Laboratory Program (2013K1A1A2A02050183).
All Science Journal Classification (ASJC) codes
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry