The first porphyrin-subphthalocyaninatoboron(III)-fused hybrid with unique conformation and intramolecular charge transfer behavior

Yuehong Zhang; Juwon Oh; Kang Wang; Dongju Shin; Xiaopeng Zhan; Yingting Zheng; Dongho Kim; Jianzhuang Jiang

doi:10.1039/c6cc05383a

The first porphyrin-subphthalocyaninatoboron(III)-fused hybrid with unique conformation and intramolecular charge transfer behavior

Yuehong Zhang, Juwon Oh, Kang Wang, Dongju Shin, Xiaopeng Zhan, Yingting Zheng, Dongho Kim, Jianzhuang Jiang

Department of Chemistry

Research output: Contribution to journal › Article

4 Citations (Scopus)

Abstract

Porphyrin and subphthalocyaninatoboron(iii) chromophores have been fused through a quinoxaline moiety, resulting in the first porphyrin-subphthalocyaninatoboron(iii)-fused hybrid with intramolecular charge transfer from tetrapyrrole/tripyrrole chromophores to the quinoxaline moiety. The unique plane-bowl molecular structure of this hybrid was revealed based on single crystal X-ray diffraction analysis for the first time.

Original language	English
Pages (from-to)	10517-10520
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	69
DOIs	https://doi.org/10.1039/c6cc05383a
Publication status	Published - 2016 Sep 7

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All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Zhang, Y., Oh, J., Wang, K., Shin, D., Zhan, X., Zheng, Y., Kim, D., & Jiang, J. (2016). The first porphyrin-subphthalocyaninatoboron(III)-fused hybrid with unique conformation and intramolecular charge transfer behavior. Chemical Communications, 52(69), 10517-10520. https://doi.org/10.1039/c6cc05383a

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abstract = "Porphyrin and subphthalocyaninatoboron(iii) chromophores have been fused through a quinoxaline moiety, resulting in the first porphyrin-subphthalocyaninatoboron(iii)-fused hybrid with intramolecular charge transfer from tetrapyrrole/tripyrrole chromophores to the quinoxaline moiety. The unique plane-bowl molecular structure of this hybrid was revealed based on single crystal X-ray diffraction analysis for the first time.",

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The first porphyrin-subphthalocyaninatoboron(III)-fused hybrid with unique conformation and intramolecular charge transfer behavior. / Zhang, Yuehong; Oh, Juwon; Wang, Kang; Shin, Dongju; Zhan, Xiaopeng; Zheng, Yingting; Kim, Dongho; Jiang, Jianzhuang.

In: Chemical Communications, Vol. 52, No. 69, 07.09.2016, p. 10517-10520.

Research output: Contribution to journal › Article

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10.1039/c6cc05383a