The invention of radical reactions. Part XXIX. Radical mono- and dideoxygenations with silanes

Derek H.R. Barton; Doo Ok Jang; Joseph Cs Jaszberenyi

doi:10.1016/S0040-4020(01)80380-X

The invention of radical reactions. Part XXIX. Radical mono- and dideoxygenations with silanes

Derek H.R. Barton, Doo Ok Jang, Joseph Cs Jaszberenyi

Chemistry and Medical Chemistry

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Thionocarbonates and xanthates of primary and secondary alcohols, as well as bis-xanthates of vic-diols are readily deoxygenated to the corresponding hydrocarbons or olefins with phenylsilane, triphenylsilane, and triethylsilane in good yield.

Original language	English
Pages (from-to)	2793-2804
Number of pages	12
Journal	Tetrahedron
Volume	49
Issue number	14
DOIs	https://doi.org/10.1016/S0040-4020(01)80380-X
Publication status	Published - 1993 Apr 2

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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AB - Thionocarbonates and xanthates of primary and secondary alcohols, as well as bis-xanthates of vic-diols are readily deoxygenated to the corresponding hydrocarbons or olefins with phenylsilane, triphenylsilane, and triethylsilane in good yield.

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The invention of radical reactions. Part XXIX. Radical mono- and dideoxygenations with silanes

Abstract

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