The invention of radical reactions. Part XXIX. Radical mono- and dideoxygenations with silanes

Derek H.R. Barton, Doo Ok Jang, Joseph Cs Jaszberenyi

Research output: Contribution to journalArticle

44 Citations (Scopus)

Abstract

Thionocarbonates and xanthates of primary and secondary alcohols, as well as bis-xanthates of vic-diols are readily deoxygenated to the corresponding hydrocarbons or olefins with phenylsilane, triphenylsilane, and triethylsilane in good yield.

Original languageEnglish
Pages (from-to)2793-2804
Number of pages12
JournalTetrahedron
Volume49
Issue number14
DOIs
Publication statusPublished - 1993 Apr 2

Fingerprint

Silanes
Alkenes
Patents and inventions
Hydrocarbons
Alcohols
triethylsilane

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Barton, Derek H.R. ; Jang, Doo Ok ; Jaszberenyi, Joseph Cs. / The invention of radical reactions. Part XXIX. Radical mono- and dideoxygenations with silanes. In: Tetrahedron. 1993 ; Vol. 49, No. 14. pp. 2793-2804.
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The invention of radical reactions. Part XXIX. Radical mono- and dideoxygenations with silanes. / Barton, Derek H.R.; Jang, Doo Ok; Jaszberenyi, Joseph Cs.

In: Tetrahedron, Vol. 49, No. 14, 02.04.1993, p. 2793-2804.

Research output: Contribution to journalArticle

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