Abstract
Various thionocarbonates and xanthates of alcohols and bis-xanthates of vic-diols are readily deoxygenated to the corresponding hydrocarbons or olefins, while bromides and iodides are dehalogenated with diphenylphenylsilane in good yield.
| Original language | English |
|---|---|
| Pages (from-to) | 7193-7214 |
| Number of pages | 22 |
| Journal | Tetrahedron |
| Volume | 49 |
| Issue number | 33 |
| DOIs | |
| Publication status | Published - 1993 Aug 13 |
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All Science Journal Classification (ASJC) codes
- Biochemistry
- Drug Discovery
- Organic Chemistry
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The invention of radical reactions. Part XXXI. Diphenylsilane : a reagent for deoxygenation of alcohols via their thiocarbonyl derivatives, deamination via isonitriles, and dehalogenation of bromo- and iodo- compounds by radical chain chemistry. / Barton, Derek H.R.; Jang, Doook; Jaszberenyi, Joseph Cs.
In: Tetrahedron, Vol. 49, No. 33, 13.08.1993, p. 7193-7214.Research output: Contribution to journal › Article
TY - JOUR
T1 - The invention of radical reactions. Part XXXI. Diphenylsilane
T2 - a reagent for deoxygenation of alcohols via their thiocarbonyl derivatives, deamination via isonitriles, and dehalogenation of bromo- and iodo- compounds by radical chain chemistry
AU - Barton, Derek H.R.
AU - Jang, Doook
AU - Jaszberenyi, Joseph Cs
PY - 1993/8/13
Y1 - 1993/8/13
N2 - Various thionocarbonates and xanthates of alcohols and bis-xanthates of vic-diols are readily deoxygenated to the corresponding hydrocarbons or olefins, while bromides and iodides are dehalogenated with diphenylphenylsilane in good yield.
AB - Various thionocarbonates and xanthates of alcohols and bis-xanthates of vic-diols are readily deoxygenated to the corresponding hydrocarbons or olefins, while bromides and iodides are dehalogenated with diphenylphenylsilane in good yield.
UR - http://www.scopus.com/inward/record.url?scp=0027291622&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0027291622&partnerID=8YFLogxK
U2 - 10.1016/S0040-4020(01)87198-2
DO - 10.1016/S0040-4020(01)87198-2
M3 - Article
AN - SCOPUS:0027291622
VL - 49
SP - 7193
EP - 7214
JO - Tetrahedron
JF - Tetrahedron
SN - 0040-4020
IS - 33
ER -