The mixed gold-palladium polyoxo-noble-metalate [NaAuIII 4PdII8O8(AsO4) 8]11-

Natalya V. Izarova, Aleksandar Kondinski, Nina Vankova, Thomas Heine, Patrick Jäger, Florian Schinle, Oliver Hampe, Ulrich Kortz

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22 Citations (Scopus)

Abstract

The first fully inorganic, discrete gold-palladium-oxo complex [NaAu III4PdII8O8(AsO 4)8]11- has been synthesized in aqueous medium. The combination of single-crystal XRD, elemental analysis, mass spectrometry, and DFT calculations allowed establishing the structure and composition of the novel polyanion, and UV/Vis studies suggest that it is stable in neutral aqueous media.

Original languageEnglish
Pages (from-to)8556-8560
Number of pages5
JournalChemistry - A European Journal
Volume20
Issue number28
DOIs
Publication statusPublished - 2014 Jul 7

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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    Izarova, N. V., Kondinski, A., Vankova, N., Heine, T., Jäger, P., Schinle, F., Hampe, O., & Kortz, U. (2014). The mixed gold-palladium polyoxo-noble-metalate [NaAuIII 4PdII8O8(AsO4) 8]11-. Chemistry - A European Journal, 20(28), 8556-8560. https://doi.org/10.1002/chem.201403032