TY - JOUR
T1 - The mixed gold-palladium polyoxo-noble-metalate [NaAuIII 4PdII8O8(AsO4) 8]11-
AU - Izarova, Natalya V.
AU - Kondinski, Aleksandar
AU - Vankova, Nina
AU - Heine, Thomas
AU - Jäger, Patrick
AU - Schinle, Florian
AU - Hampe, Oliver
AU - Kortz, Ulrich
PY - 2014/7/7
Y1 - 2014/7/7
N2 - The first fully inorganic, discrete gold-palladium-oxo complex [NaAu III4PdII8O8(AsO 4)8]11- has been synthesized in aqueous medium. The combination of single-crystal XRD, elemental analysis, mass spectrometry, and DFT calculations allowed establishing the structure and composition of the novel polyanion, and UV/Vis studies suggest that it is stable in neutral aqueous media.
AB - The first fully inorganic, discrete gold-palladium-oxo complex [NaAu III4PdII8O8(AsO 4)8]11- has been synthesized in aqueous medium. The combination of single-crystal XRD, elemental analysis, mass spectrometry, and DFT calculations allowed establishing the structure and composition of the novel polyanion, and UV/Vis studies suggest that it is stable in neutral aqueous media.
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U2 - 10.1002/chem.201403032
DO - 10.1002/chem.201403032
M3 - Article
AN - SCOPUS:84903719431
SN - 0947-6539
VL - 20
SP - 8556
EP - 8560
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 28
ER -