The modulation of Si1-xGex nanowires by correlation of inlet gas ratio with H2 gas content

Woo Jung Lee, Jin Won Ma, Jung Min Bae, Sang Han Park, Mann Ho Cho, Jae Pyung Ahn

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Si1-xGex nanowires (NWs) were prepared by a Vapor-Liquid-Solid (VLS) procedure using Au as the catalyst at a fixed growth temperature of 400 °C. The alloy composition was adjusted and the growth rate of the Si1-xGex NWs was achieved by varying the inlet gas ratio and the H2 flow rate. The growth of Si 1-xGex NWs can be explained by two mechanisms that are related to growth kinetics; first, collisional activation is a dominant factor at flow rates of H2 100 sccm and second, in the case of a H 2 flow rate of 200 sccm, the reaction is unimolecular. In addition, a Ge concentration (0.56 < x < 0.91) in Si1-xGex NWs is observed at a relatively high growth temperature of 400 °C as compared with data reported in the literature. The findings herein indicate that the high Ge concentration (x) can be attributed to the presence of interstitial Ge atoms in the Si1-xGex NWs, when they are grown under non-equilibrium conditions. This was confirmed by comparing the measured Ge concentration between EDX and XRD, Raman and strongly demonstrated by XPS results indicating the development of Ge interstitial states at lower binding energy, rather than bulk-like bonding.

Original languageEnglish
Pages (from-to)5204-5211
Number of pages8
JournalCrystEngComm
Volume13
Issue number16
DOIs
Publication statusPublished - 2011 Aug 21

Fingerprint

Nanowires
nanowires
Gases
Modulation
modulation
gases
flow velocity
Flow rate
Growth temperature
interstitials
nonequilibrium conditions
Growth kinetics
Binding energy
Energy dispersive spectroscopy
X ray photoelectron spectroscopy
binding energy
Chemical activation
Vapors
activation
vapors

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Lee, Woo Jung ; Ma, Jin Won ; Bae, Jung Min ; Park, Sang Han ; Cho, Mann Ho ; Ahn, Jae Pyung. / The modulation of Si1-xGex nanowires by correlation of inlet gas ratio with H2 gas content. In: CrystEngComm. 2011 ; Vol. 13, No. 16. pp. 5204-5211.
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The modulation of Si1-xGex nanowires by correlation of inlet gas ratio with H2 gas content. / Lee, Woo Jung; Ma, Jin Won; Bae, Jung Min; Park, Sang Han; Cho, Mann Ho; Ahn, Jae Pyung.

In: CrystEngComm, Vol. 13, No. 16, 21.08.2011, p. 5204-5211.

Research output: Contribution to journalArticle

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