The Origin of MoS2 Significantly Influences Its Performance for the Hydrogen Evolution Reaction due to Differences in Phase Purity

Xing Juan Chua, Shu Min Tan, Xinyi Chia, Zdenek Sofer, Jan Luxa, Martin Pumera

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Molybdenum disulfide (MoS2) is at the forefront of materials research. It shows great promise for electrochemical applications, especially for hydrogen evolution reaction (HER) catalysis. There is a significant discrepancy in the literature on the reported catalytic activity for HER catalysis on MoS2. Here we test the electrochemical performance of MoS2 obtained from seven sources and we show that these sources provide MoS2 of various phase purity (2H and 3R, and their mixtures) and composition, which is responsible for their different electrochemical properties. The overpotentials for HER at −10 mA cm−2 for MoS2 from seven different sources range from −0.59 V to −0.78 V vs. reversible hydrogen electrode (RHE). This is of very high importance as with much interest in 2D-MoS2, the use of the top-down approach would usually involve the application of commercially available MoS2. These commercially available MoS2 are rarely characterized for composition and phase purity. These key parameters are responsible for large variance of reported catalytic properties of MoS2.

Original languageEnglish
Pages (from-to)3169-3177
Number of pages9
JournalChemistry - A European Journal
Volume23
Issue number13
DOIs
Publication statusPublished - 2017 Jan 1

Fingerprint

Hydrogen
Catalysis
Chemical analysis
Electrochemical properties
Molybdenum
Catalyst activity
Electrodes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Organic Chemistry

Cite this

Chua, Xing Juan ; Tan, Shu Min ; Chia, Xinyi ; Sofer, Zdenek ; Luxa, Jan ; Pumera, Martin. / The Origin of MoS2 Significantly Influences Its Performance for the Hydrogen Evolution Reaction due to Differences in Phase Purity. In: Chemistry - A European Journal. 2017 ; Vol. 23, No. 13. pp. 3169-3177.
@article{06860a1ca16442f39ee1c8a42ef9ae15,
title = "The Origin of MoS2 Significantly Influences Its Performance for the Hydrogen Evolution Reaction due to Differences in Phase Purity",
abstract = "Molybdenum disulfide (MoS2) is at the forefront of materials research. It shows great promise for electrochemical applications, especially for hydrogen evolution reaction (HER) catalysis. There is a significant discrepancy in the literature on the reported catalytic activity for HER catalysis on MoS2. Here we test the electrochemical performance of MoS2 obtained from seven sources and we show that these sources provide MoS2 of various phase purity (2H and 3R, and their mixtures) and composition, which is responsible for their different electrochemical properties. The overpotentials for HER at −10 mA cm−2 for MoS2 from seven different sources range from −0.59 V to −0.78 V vs. reversible hydrogen electrode (RHE). This is of very high importance as with much interest in 2D-MoS2, the use of the top-down approach would usually involve the application of commercially available MoS2. These commercially available MoS2 are rarely characterized for composition and phase purity. These key parameters are responsible for large variance of reported catalytic properties of MoS2.",
author = "Chua, {Xing Juan} and Tan, {Shu Min} and Xinyi Chia and Zdenek Sofer and Jan Luxa and Martin Pumera",
year = "2017",
month = "1",
day = "1",
doi = "10.1002/chem.201605343",
language = "English",
volume = "23",
pages = "3169--3177",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "13",

}

The Origin of MoS2 Significantly Influences Its Performance for the Hydrogen Evolution Reaction due to Differences in Phase Purity. / Chua, Xing Juan; Tan, Shu Min; Chia, Xinyi; Sofer, Zdenek; Luxa, Jan; Pumera, Martin.

In: Chemistry - A European Journal, Vol. 23, No. 13, 01.01.2017, p. 3169-3177.

Research output: Contribution to journalArticle

TY - JOUR

T1 - The Origin of MoS2 Significantly Influences Its Performance for the Hydrogen Evolution Reaction due to Differences in Phase Purity

AU - Chua, Xing Juan

AU - Tan, Shu Min

AU - Chia, Xinyi

AU - Sofer, Zdenek

AU - Luxa, Jan

AU - Pumera, Martin

PY - 2017/1/1

Y1 - 2017/1/1

N2 - Molybdenum disulfide (MoS2) is at the forefront of materials research. It shows great promise for electrochemical applications, especially for hydrogen evolution reaction (HER) catalysis. There is a significant discrepancy in the literature on the reported catalytic activity for HER catalysis on MoS2. Here we test the electrochemical performance of MoS2 obtained from seven sources and we show that these sources provide MoS2 of various phase purity (2H and 3R, and their mixtures) and composition, which is responsible for their different electrochemical properties. The overpotentials for HER at −10 mA cm−2 for MoS2 from seven different sources range from −0.59 V to −0.78 V vs. reversible hydrogen electrode (RHE). This is of very high importance as with much interest in 2D-MoS2, the use of the top-down approach would usually involve the application of commercially available MoS2. These commercially available MoS2 are rarely characterized for composition and phase purity. These key parameters are responsible for large variance of reported catalytic properties of MoS2.

AB - Molybdenum disulfide (MoS2) is at the forefront of materials research. It shows great promise for electrochemical applications, especially for hydrogen evolution reaction (HER) catalysis. There is a significant discrepancy in the literature on the reported catalytic activity for HER catalysis on MoS2. Here we test the electrochemical performance of MoS2 obtained from seven sources and we show that these sources provide MoS2 of various phase purity (2H and 3R, and their mixtures) and composition, which is responsible for their different electrochemical properties. The overpotentials for HER at −10 mA cm−2 for MoS2 from seven different sources range from −0.59 V to −0.78 V vs. reversible hydrogen electrode (RHE). This is of very high importance as with much interest in 2D-MoS2, the use of the top-down approach would usually involve the application of commercially available MoS2. These commercially available MoS2 are rarely characterized for composition and phase purity. These key parameters are responsible for large variance of reported catalytic properties of MoS2.

UR - http://www.scopus.com/inward/record.url?scp=85012041036&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85012041036&partnerID=8YFLogxK

U2 - 10.1002/chem.201605343

DO - 10.1002/chem.201605343

M3 - Article

VL - 23

SP - 3169

EP - 3177

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 13

ER -