The oxygen-deficiency-dependent Seebeck coefficient and electrical properties of mesoporous La 0.7 Sr 0.3 MnO 3-x films

Chang Sun Park, Hong Sub Lee, Dong Il Shim, Hyung Hee Cho, Hyung-Ho Park, Kwang Ho Kwon

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The thermoelectric power factor of La 0.7 Sr 0.3 MnO 3 (LSMO) is closely related to its oxygen-deficient nature. In this study, the oxygen content of mesoporous LSMO films was controlled using various annealing atmospheres (oxygen, nitrogen, air, and argon) to investigate the relationship between oxygen deficiency and the power factor. The effect of the mesoporous structure on the power factor of the prepared LSMO films was also studied through analyses of structural and electrical properties. The oxygen-deficient state induces an increase in the lattice parameter of LSMO, which results in an increase in the electrical resistivity and an enhanced Seebeck coefficient. This phenomenon was emphasized upon the introduction of a pore structure in LSMO because of an increase of the unstable surface area. The oxygen-deficient state results in an increase in the amount of manganese in the Mn 3+ valence state and in an increase of the lattice parameter; these effects were confirmed through photoemission spectroscopic analysis. As a result, LSMO can be applied as a thermoelectric material because of the successful preparation of LSMO films with a mesoporous structure and because of the enhancement of the power factor as a consequence of increased oxygen deficiency.

Original languageEnglish
Pages (from-to)4433-4439
Number of pages7
JournalJournal of Materials Chemistry A
Volume4
Issue number12
DOIs
Publication statusPublished - 2016 Jan 1

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Seebeck coefficient
Electric properties
Oxygen
Lattice constants
Spectroscopic analysis
Argon
Thermoelectric power
Photoemission
Manganese
Pore structure
Structural properties
Nitrogen
Annealing
Air

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

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title = "The oxygen-deficiency-dependent Seebeck coefficient and electrical properties of mesoporous La 0.7 Sr 0.3 MnO 3-x films",
abstract = "The thermoelectric power factor of La 0.7 Sr 0.3 MnO 3 (LSMO) is closely related to its oxygen-deficient nature. In this study, the oxygen content of mesoporous LSMO films was controlled using various annealing atmospheres (oxygen, nitrogen, air, and argon) to investigate the relationship between oxygen deficiency and the power factor. The effect of the mesoporous structure on the power factor of the prepared LSMO films was also studied through analyses of structural and electrical properties. The oxygen-deficient state induces an increase in the lattice parameter of LSMO, which results in an increase in the electrical resistivity and an enhanced Seebeck coefficient. This phenomenon was emphasized upon the introduction of a pore structure in LSMO because of an increase of the unstable surface area. The oxygen-deficient state results in an increase in the amount of manganese in the Mn 3+ valence state and in an increase of the lattice parameter; these effects were confirmed through photoemission spectroscopic analysis. As a result, LSMO can be applied as a thermoelectric material because of the successful preparation of LSMO films with a mesoporous structure and because of the enhancement of the power factor as a consequence of increased oxygen deficiency.",
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The oxygen-deficiency-dependent Seebeck coefficient and electrical properties of mesoporous La 0.7 Sr 0.3 MnO 3-x films . / Park, Chang Sun; Lee, Hong Sub; Shim, Dong Il; Cho, Hyung Hee; Park, Hyung-Ho; Kwon, Kwang Ho.

In: Journal of Materials Chemistry A, Vol. 4, No. 12, 01.01.2016, p. 4433-4439.

Research output: Contribution to journalArticle

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