The polyoxo-22-palladate(II), [Na2Pd II 22 O12(AsVO4)15(AsVO3OH)]25-

Natalya V. Izarova, Zhengguo Lin, Peng Yang, Aleksandar Kondinski, Nina Vankova, Thomas Heine, Ulrich Kortz

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10 Citations (Scopus)

Abstract

The polyoxo-22-palladate [Na2PdII22O12(AsVO4)15(AsVO3OH)]25- (1), which represents a novel polyoxo-noble-metalate structural type, was synthesized by reaction of Pd2+ and AsO43- ions in aqueous solution. Polyanion 1 comprises two {NaPd11} units linked by two arsenate bridges, and hence represents the first example of a defect, monolacunary {Pd11} polyoxopalladate nanocube with arsenate capping groups. The title polyanion was characterized in the solid state as well as by theoretical calculations.

Original languageEnglish
Pages (from-to)2394-2398
Number of pages5
JournalDalton Transactions
Volume45
Issue number6
DOIs
Publication statusPublished - 2016 Jan 1

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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    Izarova, N. V., Lin, Z., Yang, P., Kondinski, A., Vankova, N., Heine, T., & Kortz, U. (2016). The polyoxo-22-palladate(II), [Na2Pd II 22 O12(AsVO4)15(AsVO3OH)]25-. Dalton Transactions, 45(6), 2394-2398. https://doi.org/10.1039/c5dt04526f