Abstract
The film formation and crosslinking of complementary reactive nanoparticle blends of acetoacetoxy (or acetoacctamido) functional particles with isocyanate functional particles were investigated using attenuated total reflectance-Fourier transform infared (ATR-FTIR) spectroscopy. A series of copolymers of 2-ethylhexyl methacrylate (EHMA) with acetoacetoxy ethyl methacrylate (AA), 2-methyl-acrylic acid 2-methyl-2-(3-oxo-butyrylamino)-propyl ester (AM), and dimethyl meta-isopropenyl benzyl isocyanate (TMI) were prepared by emulsion polymerization techniques at room temperature. These blends were air-dried on ATR-FTIR germanium (Ge) discs while the FTIR spectra were taken during the film formation process. The interfacial crosslinking reaction between functional moieties during the film formation process was determined using the FTIR data. The reactivity of acetoacetamido group is higher than that of acetoacetoxy group and the rate constant for the crosslinking reaction between two reaction moieties of terpolymer samples is higher as compared to the blended systems.
| Original language | English |
|---|---|
| Pages (from-to) | 537-545 |
| Number of pages | 9 |
| Journal | Journal of Dispersion Science and Technology |
| Volume | 24 |
| Issue number | 3-4 |
| DOIs | |
| Publication status | Published - 2003 May 1 |
Fingerprint
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Surfaces, Coatings and Films
- Polymers and Plastics
Cite this
}
The use of ATR-FTIR to determine the effects of functional groups on interfacial crosslinking of reactive nanoparticles. / Park, Young Jun; Kim, Jung Hyun.
In: Journal of Dispersion Science and Technology, Vol. 24, No. 3-4, 01.05.2003, p. 537-545.Research output: Contribution to journal › Article
TY - JOUR
T1 - The use of ATR-FTIR to determine the effects of functional groups on interfacial crosslinking of reactive nanoparticles
AU - Park, Young Jun
AU - Kim, Jung Hyun
PY - 2003/5/1
Y1 - 2003/5/1
N2 - The film formation and crosslinking of complementary reactive nanoparticle blends of acetoacetoxy (or acetoacctamido) functional particles with isocyanate functional particles were investigated using attenuated total reflectance-Fourier transform infared (ATR-FTIR) spectroscopy. A series of copolymers of 2-ethylhexyl methacrylate (EHMA) with acetoacetoxy ethyl methacrylate (AA), 2-methyl-acrylic acid 2-methyl-2-(3-oxo-butyrylamino)-propyl ester (AM), and dimethyl meta-isopropenyl benzyl isocyanate (TMI) were prepared by emulsion polymerization techniques at room temperature. These blends were air-dried on ATR-FTIR germanium (Ge) discs while the FTIR spectra were taken during the film formation process. The interfacial crosslinking reaction between functional moieties during the film formation process was determined using the FTIR data. The reactivity of acetoacetamido group is higher than that of acetoacetoxy group and the rate constant for the crosslinking reaction between two reaction moieties of terpolymer samples is higher as compared to the blended systems.
AB - The film formation and crosslinking of complementary reactive nanoparticle blends of acetoacetoxy (or acetoacctamido) functional particles with isocyanate functional particles were investigated using attenuated total reflectance-Fourier transform infared (ATR-FTIR) spectroscopy. A series of copolymers of 2-ethylhexyl methacrylate (EHMA) with acetoacetoxy ethyl methacrylate (AA), 2-methyl-acrylic acid 2-methyl-2-(3-oxo-butyrylamino)-propyl ester (AM), and dimethyl meta-isopropenyl benzyl isocyanate (TMI) were prepared by emulsion polymerization techniques at room temperature. These blends were air-dried on ATR-FTIR germanium (Ge) discs while the FTIR spectra were taken during the film formation process. The interfacial crosslinking reaction between functional moieties during the film formation process was determined using the FTIR data. The reactivity of acetoacetamido group is higher than that of acetoacetoxy group and the rate constant for the crosslinking reaction between two reaction moieties of terpolymer samples is higher as compared to the blended systems.
UR - http://www.scopus.com/inward/record.url?scp=0042239386&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0042239386&partnerID=8YFLogxK
U2 - 10.1081/DIS-120021808
DO - 10.1081/DIS-120021808
M3 - Article
VL - 24
SP - 537
EP - 545
JO - Journal of Dispersion Science and Technology
JF - Journal of Dispersion Science and Technology
SN - 0193-2691
IS - 3-4
ER -