Thermal properties and microencapsulation of a phosphate flame retardant with a epoxy resin

Kyung Hyun Baek, Jun Young Lee, Sang Hyun Hong, Jung Hyun Kim

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4 Citations (Scopus)

Abstract

The microcapsules containing triphenyl phosphate (TPP), a flame retardant, were prepared by phase-inversion emulsification technique using the epoxy resin (Novolac type) with excellent physical properties and network structure. This microencapsulation process was adopted for the protection of TPP evaporation and wetting of polymer composite during the polymer blend processing. The TPP, epoxy resin and mixed surfactants were emulsified to oil in water (O/W) by the phase inversion technology and then conducted on the crosslinking of epoxy resin by in-situ polymerization. The capsule size and size distribution of TPP capsules was controlled by mixed surfactant ratio, concentration and TPP contents. The formation and thermal property of TPP capsules were measured by differential scanning calorimetry and thermogravimetric analysis. The morphology and size of TPP capsules were also investigated by scanning and transmission electron microscopies. As the surfactant concentration increased, the TPP capsules were more spherical and mono-dispersed at the same weight ratio of mixed surfactants (F127 : SDBS).

Original languageEnglish
Pages (from-to)404-411
Number of pages8
JournalPolymer (Korea)
Volume28
Issue number5
Publication statusPublished - 2004 Sep 1

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All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Polymers and Plastics
  • Materials Chemistry

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