Thermal stability of the sensing properties in H2 sensors composed of Pd nanogaps on an Elastomeric Substrate

Byungjin Jang, Wonkung Kim, Min Jung Song, Wooyoung Lee

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The influence of thermal exposure on sensing properties of H2 sensor based on Pd MOTIFE (highly mobile palladium thin films on an elastomer) was investigated. This sensor was fabricated on a Poly(dimethylsiloxane) (PDMS) substrate and its Pd nanogaps were obtained through mechanical stretching and H2 exposure. When the substrates were annealed at 80–200 °C, wrinkles were formed to release the stress due to the mismatch of the thermal expansion coefficients between the PDMS layer and the Pd film. The wrinkling wavelength and the compressive stress of the Pd/PDMS layers were estimated using simple equations as a function of the annealing temperature. The width of the Pd nanogaps of the annealed samples was measured using SEM analysis. Higher annealing temperatures led to a decrease in the wrinkling wavelength and an increase in the width of the Pd nanogap. This was attributed to increases in the individual variation of the compressive stress and strain between PDMS and the Pd/PDMS layers. The enlarged Pd nanogap contributed to a decrease in the performance of the sensor. Nevertheless, the Pd sensor exhibited perfectly on-off operation with a response time of less than 1 s when annealed at temperatures up to 100 °C.

Original languageEnglish
Pages (from-to)186-192
Number of pages7
JournalSensors and Actuators, B: Chemical
Volume240
DOIs
Publication statusPublished - 2017 Mar 1

Fingerprint

Polydimethylsiloxane
Thermodynamic stability
thermal stability
wrinkling
sensors
Sensors
Substrates
Compressive stress
annealing
Annealing
Elastomers
elastomers
Wavelength
wavelengths
temperature
Palladium
palladium
thermal expansion
Temperature
Stretching

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Instrumentation
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Electrical and Electronic Engineering
  • Materials Chemistry

Cite this

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abstract = "The influence of thermal exposure on sensing properties of H2 sensor based on Pd MOTIFE (highly mobile palladium thin films on an elastomer) was investigated. This sensor was fabricated on a Poly(dimethylsiloxane) (PDMS) substrate and its Pd nanogaps were obtained through mechanical stretching and H2 exposure. When the substrates were annealed at 80–200 °C, wrinkles were formed to release the stress due to the mismatch of the thermal expansion coefficients between the PDMS layer and the Pd film. The wrinkling wavelength and the compressive stress of the Pd/PDMS layers were estimated using simple equations as a function of the annealing temperature. The width of the Pd nanogaps of the annealed samples was measured using SEM analysis. Higher annealing temperatures led to a decrease in the wrinkling wavelength and an increase in the width of the Pd nanogap. This was attributed to increases in the individual variation of the compressive stress and strain between PDMS and the Pd/PDMS layers. The enlarged Pd nanogap contributed to a decrease in the performance of the sensor. Nevertheless, the Pd sensor exhibited perfectly on-off operation with a response time of less than 1 s when annealed at temperatures up to 100 °C.",
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Thermal stability of the sensing properties in H2 sensors composed of Pd nanogaps on an Elastomeric Substrate. / Jang, Byungjin; Kim, Wonkung; Song, Min Jung; Lee, Wooyoung.

In: Sensors and Actuators, B: Chemical, Vol. 240, 01.03.2017, p. 186-192.

Research output: Contribution to journalArticle

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