Thermally reduced graphenes exhibiting a close relationship to amorphous carbon

Colin Hong An Wong, Adriano Ambrosi, Martin Pumera

Research output: Contribution to journalArticle

55 Citations (Scopus)

Abstract

Graphene is an important material for sensing and energy storage applications. Since the vast majority of sensing and energy storage chemical and electrochemical systems require bulk quantities of graphene, thermally reduced graphene oxide (TRGO) is commonly employed instead of pristine graphene. The sp 2 planar structure of TRGO is heavily damaged, consisting of a very short sp 2 crystallite size of nanometre length and with areas of sp 3 hybridized carbon. Such a structure of TRGO is reminiscent of the key characteristic of the structure of amorphous carbon, which is defined as a material without long-range crystalline order consisting of both sp 2 and sp 3 hybridized carbons. Herein, we describe the characterization of TRGO, its parent graphite material and carbon black (a form of amorphous carbon) via transmission electron microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and cyclic voltammetry experiments. We used the data obtained as well as consideration of practical factors to perform a comparative assessment of the relative electrochemical performances of TRGO against amorphous carbon. We found out that TRGO and amorphous carbon exhibit almost identical characteristics in terms of density of defects in the sp 2 lattice and a similar crystallite size as determined by Raman spectroscopy. These two materials also exhibit similar amounts of oxygen containing groups as determined by XPS and nearly indistinguishable cyclic voltammetric response providing almost identical heterogeneous electron transfer constants. This leads us to conclude that for some sensing and energy storage electrochemical applications, the use of amorphous carbon might be a much more economical solution than the one requiring digestion of highly crystalline graphite with strong oxidants to graphite oxide and then thermally exfoliating it to thermally reduced graphene oxide.

Original languageEnglish
Pages (from-to)4972-4977
Number of pages6
JournalNanoscale
Volume4
Issue number16
DOIs
Publication statusPublished - 2012 Aug 21

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Graphite
Amorphous carbon
Graphene
Oxides
Energy storage
Crystallite size
Raman spectroscopy
X ray photoelectron spectroscopy
Crystalline materials
Carbon
Soot
Carbon black
Oxidants
Cyclic voltammetry
Transmission electron microscopy
Defects
Oxygen

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

An Wong, Colin Hong ; Ambrosi, Adriano ; Pumera, Martin. / Thermally reduced graphenes exhibiting a close relationship to amorphous carbon. In: Nanoscale. 2012 ; Vol. 4, No. 16. pp. 4972-4977.
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Thermally reduced graphenes exhibiting a close relationship to amorphous carbon. / An Wong, Colin Hong; Ambrosi, Adriano; Pumera, Martin.

In: Nanoscale, Vol. 4, No. 16, 21.08.2012, p. 4972-4977.

Research output: Contribution to journalArticle

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