Thermochemical Decomposition of Microcrystalline Cellulose Using Sub- and Supercritical Tetralin and Decalin with Fe3O4

Anton Koriakin, Hai Van Nguyen, Doo Wook Kim, Chang Ha Lee

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Direct thermochemical liquefaction of microcrystalline cellulose was investigated in sub- and supercritical solvents in a batch reactor. The liquefaction efficiency of hydrogen donor solvents (tetralin and decalin) was compared to that of m-xylene. Tetralin was the most effective solvent with respect to the conversion at every tested condition starting from 350 °C. At 400 °C, the total conversion of cellulose in tetralin approached 96.8-98.3% with a negligible amount of char formation. The pressure of hydrogen had little effect on conversion for any solvent, while the addition of iron oxide catalyst (Fe3O4) led to improved conversion and liquid yield from the reaction compared to reactions without the catalyst at temperatures higher than 350 °C. Hydrogen pressure in the presence of iron oxide catalyst significantly suppressed the char formation and improved liquid production. The thermal-treated chars collected after liquefaction reactions showed a fair adsorption capacity of CO2 compared to activated carbon.

Original languageEnglish
Pages (from-to)5184-5194
Number of pages11
JournalIndustrial and Engineering Chemistry Research
Volume54
Issue number18
DOIs
Publication statusPublished - 2015 May 13

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Cellulose
Liquefaction
Decomposition
Hydrogen
Iron oxides
Catalysts
Batch reactors
Liquids
Xylene
Activated carbon
Adsorption
decalin
microcrystalline cellulose
tetralin
Temperature
ferric oxide

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

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abstract = "Direct thermochemical liquefaction of microcrystalline cellulose was investigated in sub- and supercritical solvents in a batch reactor. The liquefaction efficiency of hydrogen donor solvents (tetralin and decalin) was compared to that of m-xylene. Tetralin was the most effective solvent with respect to the conversion at every tested condition starting from 350 °C. At 400 °C, the total conversion of cellulose in tetralin approached 96.8-98.3{\%} with a negligible amount of char formation. The pressure of hydrogen had little effect on conversion for any solvent, while the addition of iron oxide catalyst (Fe3O4) led to improved conversion and liquid yield from the reaction compared to reactions without the catalyst at temperatures higher than 350 °C. Hydrogen pressure in the presence of iron oxide catalyst significantly suppressed the char formation and improved liquid production. The thermal-treated chars collected after liquefaction reactions showed a fair adsorption capacity of CO2 compared to activated carbon.",
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Thermochemical Decomposition of Microcrystalline Cellulose Using Sub- and Supercritical Tetralin and Decalin with Fe3O4. / Koriakin, Anton; Nguyen, Hai Van; Kim, Doo Wook; Lee, Chang Ha.

In: Industrial and Engineering Chemistry Research, Vol. 54, No. 18, 13.05.2015, p. 5184-5194.

Research output: Contribution to journalArticle

TY - JOUR

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