Abstract
The solubility of carbon in the MO-B2O3 (MO = CaO, BaO, and Na2O) and CaO-RO (RO = SiO2 and Al2O3) slags at high temperatures was measured to understand the thermodynamic behavior of carbon in molten slags. The solubility of carbon as a function of the composition of slags shows a minimum value, indicating that carbon dissolves by different mechanisms in the acidic and basic slags, respectively. The infrared spectra measurements indicate that the B-C bond is about 1150 and 1140 cm-1 in the acidic region of the CaO-B2O3 and Na2O-B2O3 slags; hence, the incorporation of carbon into the borate network is confirmed qualitatively. The dissolution of carbon and nitrogen into the slags shows a similar behavior in the B2O3-bearing slags, while the different behavior is shown in the CaO-SiO2 and CaO-Al2O3 slags, based on the relationship between carbide capacity and nitride capacity.
| Original language | English |
|---|---|
| Journal | ISIJ International |
| Volume | 40 |
| Issue number | SUPPL. |
| Publication status | Published - 2000 Dec 1 |
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All Science Journal Classification (ASJC) codes
- Mechanics of Materials
- Mechanical Engineering
- Metals and Alloys
- Materials Chemistry
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Thermodynamic behavior of carbon in molten slags. / Park, Joo Hyun; Min, Dong Joon.
In: ISIJ International, Vol. 40, No. SUPPL., 01.12.2000.Research output: Contribution to journal › Article
TY - JOUR
T1 - Thermodynamic behavior of carbon in molten slags
AU - Park, Joo Hyun
AU - Min, Dong Joon
PY - 2000/12/1
Y1 - 2000/12/1
N2 - The solubility of carbon in the MO-B2O3 (MO = CaO, BaO, and Na2O) and CaO-RO (RO = SiO2 and Al2O3) slags at high temperatures was measured to understand the thermodynamic behavior of carbon in molten slags. The solubility of carbon as a function of the composition of slags shows a minimum value, indicating that carbon dissolves by different mechanisms in the acidic and basic slags, respectively. The infrared spectra measurements indicate that the B-C bond is about 1150 and 1140 cm-1 in the acidic region of the CaO-B2O3 and Na2O-B2O3 slags; hence, the incorporation of carbon into the borate network is confirmed qualitatively. The dissolution of carbon and nitrogen into the slags shows a similar behavior in the B2O3-bearing slags, while the different behavior is shown in the CaO-SiO2 and CaO-Al2O3 slags, based on the relationship between carbide capacity and nitride capacity.
AB - The solubility of carbon in the MO-B2O3 (MO = CaO, BaO, and Na2O) and CaO-RO (RO = SiO2 and Al2O3) slags at high temperatures was measured to understand the thermodynamic behavior of carbon in molten slags. The solubility of carbon as a function of the composition of slags shows a minimum value, indicating that carbon dissolves by different mechanisms in the acidic and basic slags, respectively. The infrared spectra measurements indicate that the B-C bond is about 1150 and 1140 cm-1 in the acidic region of the CaO-B2O3 and Na2O-B2O3 slags; hence, the incorporation of carbon into the borate network is confirmed qualitatively. The dissolution of carbon and nitrogen into the slags shows a similar behavior in the B2O3-bearing slags, while the different behavior is shown in the CaO-SiO2 and CaO-Al2O3 slags, based on the relationship between carbide capacity and nitride capacity.
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UR - http://www.scopus.com/inward/citedby.url?scp=1942459573&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:1942459573
VL - 40
JO - ISIJ International
JF - ISIJ International
SN - 0915-1559
IS - SUPPL.
ER -