Thermodynamic determination of solvation potentials of divalent metal chlorides (MCl2) in iso-dielectric media by EMF measurements

Manjula Spah, Dal Chand Spah, Joonho Lee, Ho Jun Song, Jin Won Park

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Cell potentials (EMF) of metal chlorides (CoCl2 and CuCl2) were measured at T = (303.15 and 313.15) K on the cell: MX Hg|MCl2 (m) in solvent S|AgCl-Ag, where S = water or iso-dielectric media with water of FD + DMF or FD + D. Stock solutions of metal chlorides were prepared by mass in water/iso-dielectric solvents. There was a change in the EMF values in these iso-dielectric media from its pure components. This change of EMF was associated with the change of ion-solvent interactions and was explained on the basis of kinetics of electrode processes. Equilibrium constants (K1 and K2) as well as the degrees of dissociation (α1 and α2) values for two step dissociation of metal chlorides in these solvents were obtained by iterative procedures. The standard electrode potential (E°) values of the above cell were calculated in these solvents, and same were used to get the mean ionic activity coefficients (γ±) and standard thermodynamic functions (ΔG°, ΔH°, and ΔS°) of MCl2. The E° values were also used to compute the standard molar Gibbs free energy of transfer (Δ Gtr {ring operator}) and other transfer thermodynamic parameters (Δ Htr {ring operator} and Δ Str {ring operator}) of MCl2 from water to iso-dielectric media.

Original languageEnglish
Pages (from-to)598-603
Number of pages6
JournalJournal of Chemical Thermodynamics
Volume41
Issue number5
DOIs
Publication statusPublished - 2009 May 1

Fingerprint

Solvation
solvation
Chlorides
Metals
chlorides
Thermodynamics
thermodynamics
Electric potential
metals
Water
operators
water
rings
cells
dissociation
Electrodes
electrodes
Activity coefficients
Equilibrium constants
Gibbs free energy

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Atomic and Molecular Physics, and Optics
  • Materials Science(all)

Cite this

@article{60ff718fe1b643279e278fa494008519,
title = "Thermodynamic determination of solvation potentials of divalent metal chlorides (MCl2) in iso-dielectric media by EMF measurements",
abstract = "Cell potentials (EMF) of metal chlorides (CoCl2 and CuCl2) were measured at T = (303.15 and 313.15) K on the cell: MX Hg|MCl2 (m) in solvent S|AgCl-Ag, where S = water or iso-dielectric media with water of FD + DMF or FD + D. Stock solutions of metal chlorides were prepared by mass in water/iso-dielectric solvents. There was a change in the EMF values in these iso-dielectric media from its pure components. This change of EMF was associated with the change of ion-solvent interactions and was explained on the basis of kinetics of electrode processes. Equilibrium constants (K1 and K2) as well as the degrees of dissociation (α1 and α2) values for two step dissociation of metal chlorides in these solvents were obtained by iterative procedures. The standard electrode potential (E°) values of the above cell were calculated in these solvents, and same were used to get the mean ionic activity coefficients (γ±) and standard thermodynamic functions (ΔG°, ΔH°, and ΔS°) of MCl2. The E° values were also used to compute the standard molar Gibbs free energy of transfer (Δ Gtr {ring operator}) and other transfer thermodynamic parameters (Δ Htr {ring operator} and Δ Str {ring operator}) of MCl2 from water to iso-dielectric media.",
author = "Manjula Spah and Spah, {Dal Chand} and Joonho Lee and Song, {Ho Jun} and Park, {Jin Won}",
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Thermodynamic determination of solvation potentials of divalent metal chlorides (MCl2) in iso-dielectric media by EMF measurements. / Spah, Manjula; Spah, Dal Chand; Lee, Joonho; Song, Ho Jun; Park, Jin Won.

In: Journal of Chemical Thermodynamics, Vol. 41, No. 5, 01.05.2009, p. 598-603.

Research output: Contribution to journalArticle

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T1 - Thermodynamic determination of solvation potentials of divalent metal chlorides (MCl2) in iso-dielectric media by EMF measurements

AU - Spah, Manjula

AU - Spah, Dal Chand

AU - Lee, Joonho

AU - Song, Ho Jun

AU - Park, Jin Won

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N2 - Cell potentials (EMF) of metal chlorides (CoCl2 and CuCl2) were measured at T = (303.15 and 313.15) K on the cell: MX Hg|MCl2 (m) in solvent S|AgCl-Ag, where S = water or iso-dielectric media with water of FD + DMF or FD + D. Stock solutions of metal chlorides were prepared by mass in water/iso-dielectric solvents. There was a change in the EMF values in these iso-dielectric media from its pure components. This change of EMF was associated with the change of ion-solvent interactions and was explained on the basis of kinetics of electrode processes. Equilibrium constants (K1 and K2) as well as the degrees of dissociation (α1 and α2) values for two step dissociation of metal chlorides in these solvents were obtained by iterative procedures. The standard electrode potential (E°) values of the above cell were calculated in these solvents, and same were used to get the mean ionic activity coefficients (γ±) and standard thermodynamic functions (ΔG°, ΔH°, and ΔS°) of MCl2. The E° values were also used to compute the standard molar Gibbs free energy of transfer (Δ Gtr {ring operator}) and other transfer thermodynamic parameters (Δ Htr {ring operator} and Δ Str {ring operator}) of MCl2 from water to iso-dielectric media.

AB - Cell potentials (EMF) of metal chlorides (CoCl2 and CuCl2) were measured at T = (303.15 and 313.15) K on the cell: MX Hg|MCl2 (m) in solvent S|AgCl-Ag, where S = water or iso-dielectric media with water of FD + DMF or FD + D. Stock solutions of metal chlorides were prepared by mass in water/iso-dielectric solvents. There was a change in the EMF values in these iso-dielectric media from its pure components. This change of EMF was associated with the change of ion-solvent interactions and was explained on the basis of kinetics of electrode processes. Equilibrium constants (K1 and K2) as well as the degrees of dissociation (α1 and α2) values for two step dissociation of metal chlorides in these solvents were obtained by iterative procedures. The standard electrode potential (E°) values of the above cell were calculated in these solvents, and same were used to get the mean ionic activity coefficients (γ±) and standard thermodynamic functions (ΔG°, ΔH°, and ΔS°) of MCl2. The E° values were also used to compute the standard molar Gibbs free energy of transfer (Δ Gtr {ring operator}) and other transfer thermodynamic parameters (Δ Htr {ring operator} and Δ Str {ring operator}) of MCl2 from water to iso-dielectric media.

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