Abstract
Excess molar volumes, V E 123 of 1,3-dioxolane or 1,4-dioxane (1) + benzene or toluene (2) + formamide or + N,N-dimethylformamide (3) ternary mixtures at 308.15 K and at atmospheric pressure have been determined dilatometrically over the entire composition range. The excess molar volumes data of these ternary systems were fitted to the Redlich-Kister equation. The data have been analyzed in terms of Graph theory (model) to understand the nature and strength of molecular interactions existing in these mixtures. It has been observed that V E 123 values predicted by Graph theory compare well with their corresponding experimental values.
| Original language | English |
|---|---|
| Pages (from-to) | 680-691 |
| Number of pages | 12 |
| Journal | Journal of Solution Chemistry |
| Volume | 39 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 2010 May 1 |
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All Science Journal Classification (ASJC) codes
- Biophysics
- Biochemistry
- Molecular Biology
- Physical and Theoretical Chemistry
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Thermodynamic investigation of molecular interactions in 1,3-dioxolane or 1,4-dioxane + benzene or toluene + formamide or +N,N-dimethylformamide ternary mixtures at 308.15 K and atmospheric pressure. / Kumar, Satish; Sharma, V. K.; Yadav, J. S.; Moon, il.
In: Journal of Solution Chemistry, Vol. 39, No. 5, 01.05.2010, p. 680-691.Research output: Contribution to journal › Article
TY - JOUR
T1 - Thermodynamic investigation of molecular interactions in 1,3-dioxolane or 1,4-dioxane + benzene or toluene + formamide or +N,N-dimethylformamide ternary mixtures at 308.15 K and atmospheric pressure
AU - Kumar, Satish
AU - Sharma, V. K.
AU - Yadav, J. S.
AU - Moon, il
PY - 2010/5/1
Y1 - 2010/5/1
N2 - Excess molar volumes, V E 123 of 1,3-dioxolane or 1,4-dioxane (1) + benzene or toluene (2) + formamide or + N,N-dimethylformamide (3) ternary mixtures at 308.15 K and at atmospheric pressure have been determined dilatometrically over the entire composition range. The excess molar volumes data of these ternary systems were fitted to the Redlich-Kister equation. The data have been analyzed in terms of Graph theory (model) to understand the nature and strength of molecular interactions existing in these mixtures. It has been observed that V E 123 values predicted by Graph theory compare well with their corresponding experimental values.
AB - Excess molar volumes, V E 123 of 1,3-dioxolane or 1,4-dioxane (1) + benzene or toluene (2) + formamide or + N,N-dimethylformamide (3) ternary mixtures at 308.15 K and at atmospheric pressure have been determined dilatometrically over the entire composition range. The excess molar volumes data of these ternary systems were fitted to the Redlich-Kister equation. The data have been analyzed in terms of Graph theory (model) to understand the nature and strength of molecular interactions existing in these mixtures. It has been observed that V E 123 values predicted by Graph theory compare well with their corresponding experimental values.
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U2 - 10.1007/s10953-010-9526-9
DO - 10.1007/s10953-010-9526-9
M3 - Article
VL - 39
SP - 680
EP - 691
JO - Journal of Solution Chemistry
JF - Journal of Solution Chemistry
SN - 0095-9782
IS - 5
ER -