Thermodynamic investigation of molecular interactions in 1,3-dioxolane or 1,4-dioxane + benzene or toluene + formamide or +N,N-dimethylformamide ternary mixtures at 308.15 K and atmospheric pressure

Satish Kumar, V. K. Sharma, J. S. Yadav, Il Moon

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Excess molar volumes, V E 123 of 1,3-dioxolane or 1,4-dioxane (1) + benzene or toluene (2) + formamide or + N,N-dimethylformamide (3) ternary mixtures at 308.15 K and at atmospheric pressure have been determined dilatometrically over the entire composition range. The excess molar volumes data of these ternary systems were fitted to the Redlich-Kister equation. The data have been analyzed in terms of Graph theory (model) to understand the nature and strength of molecular interactions existing in these mixtures. It has been observed that V E 123 values predicted by Graph theory compare well with their corresponding experimental values.

Original languageEnglish
Pages (from-to)680-691
Number of pages12
JournalJournal of Solution Chemistry
Volume39
Issue number5
DOIs
Publication statusPublished - 2010 May

All Science Journal Classification (ASJC) codes

  • Biophysics
  • Biochemistry
  • Molecular Biology
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Thermodynamic investigation of molecular interactions in 1,3-dioxolane or 1,4-dioxane + benzene or toluene + formamide or +N,N-dimethylformamide ternary mixtures at 308.15 K and atmospheric pressure'. Together they form a unique fingerprint.

  • Cite this