Thermodynamic of phosphorus in FeO-MnO-CaO-SiO2- MgOsatd. Slag systems

Moon Kyung Cho, Kyung Ho Park, Dong Joon Min

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Recently, new extraction technology for manganese nodule has been developed as alternative noble metallic resources. It is important to understand thermodynamic behaviors of phosphorus in low basic slag system from the viewpoint of the refining processing optimization. Thermodynamic behaviors of phosphorus in the FeO-MnO-CaO-SiO2-MgOsatd. slag system were investigated at 1723 K with various oxygen potential and slag composition of low basicity. The experimental results for dependence of phosphorus on oxygen potential and slag basicity indicated that the dissolution mechanism of phosphorus into slag of low basicity could be derived as follows; [P]+5/4O2+(O2-)= (PO3.5 2-) Present experimental results implied that stability of phosphorus in slag would be depended on both of O2- (basicity) and content of Ca2+ in molten slag. The thermodynamic effect of FeO, MnO and Na2O on low basicity on phosphate capacity was discussed.

Original languageEnglish
Pages (from-to)188-194
Number of pages7
JournalJournal of Korean Institute of Metals and Materials
Volume47
Issue number3
Publication statusPublished - 2009 Mar 1

Fingerprint

Phosphorus
SiO2
Slags
Thermodynamics
Alkalinity
Oxygen
Manganese
Nodule
Dissolution
Experimental Results
Manganese nodules
Phosphate
Refining
Molten materials
Resources
Optimization
Phosphates
Alternatives
Processing
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Modelling and Simulation
  • Surfaces, Coatings and Films
  • Metals and Alloys

Cite this

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abstract = "Recently, new extraction technology for manganese nodule has been developed as alternative noble metallic resources. It is important to understand thermodynamic behaviors of phosphorus in low basic slag system from the viewpoint of the refining processing optimization. Thermodynamic behaviors of phosphorus in the FeO-MnO-CaO-SiO2-MgOsatd. slag system were investigated at 1723 K with various oxygen potential and slag composition of low basicity. The experimental results for dependence of phosphorus on oxygen potential and slag basicity indicated that the dissolution mechanism of phosphorus into slag of low basicity could be derived as follows; [P]+5/4O2+(O2-)= (PO3.5 2-) Present experimental results implied that stability of phosphorus in slag would be depended on both of O2- (basicity) and content of Ca2+ in molten slag. The thermodynamic effect of FeO, MnO and Na2O on low basicity on phosphate capacity was discussed.",
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Thermodynamic of phosphorus in FeO-MnO-CaO-SiO2- MgOsatd. Slag systems. / Cho, Moon Kyung; Park, Kyung Ho; Min, Dong Joon.

In: Journal of Korean Institute of Metals and Materials, Vol. 47, No. 3, 01.03.2009, p. 188-194.

Research output: Contribution to journalArticle

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AU - Park, Kyung Ho

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AB - Recently, new extraction technology for manganese nodule has been developed as alternative noble metallic resources. It is important to understand thermodynamic behaviors of phosphorus in low basic slag system from the viewpoint of the refining processing optimization. Thermodynamic behaviors of phosphorus in the FeO-MnO-CaO-SiO2-MgOsatd. slag system were investigated at 1723 K with various oxygen potential and slag composition of low basicity. The experimental results for dependence of phosphorus on oxygen potential and slag basicity indicated that the dissolution mechanism of phosphorus into slag of low basicity could be derived as follows; [P]+5/4O2+(O2-)= (PO3.5 2-) Present experimental results implied that stability of phosphorus in slag would be depended on both of O2- (basicity) and content of Ca2+ in molten slag. The thermodynamic effect of FeO, MnO and Na2O on low basicity on phosphate capacity was discussed.

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