Thermodynamic properties of manganese oxide in BOF slags

Sung Mo Jung, Chang Hee Rhee, Dong Joon Min

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

It is necessary to understand the thermodynamic properties of MnO in steelmaking slags for the smelting reduction of Mn ore in BOF process. Studies of the manganese distribution between CaO-SiO2-FetO-MnO slags and liquid silver in equilibrium with solid Fe in the temperature range of 1 623 to 1 723 K were carried out under a CO/CO2 atmosphere. The FetO content in (32.4∼36.3)%CaO-(31.6∼44.0)%SiO2- (9.9∼24.1)%FeO-(0.4∼2.6)%Fe2O3-(8.9∼10.8)% MnO slags was found to have a linear relationship with oxygen partial pressure. The values of Fe3+/Fe2+ in the same slag system increase by increasing the FetO content. The Mn distribution ratio between slag and metal, (%MnO)/[%MN]Fe-Csat, increases with FeO content in a linear relationship over the measured FeO concentration range (6.7-24.1 mass%). The Mn distribution ratio decreases with increasing CaF2, which is believed to have the effect of increasing the activities of MnO and FeO. Temperature dependence of equilibrium manganese distribution at pO2 = 6.6 × 10-12 atm in the temperature range of 1 623 to 1 723 K can be expressed as follows: log (MnO)/[%Mn]Fe-Csat = 14 270/T - 6.55 The relative partial heat of solution of MnO into (32.7∼39.1) %CaO-(32.7∼38.8)%SiO2-(10.2∼20.2∼20.78)%FeO- (1.0∼2.4)%Fe2O3-(9.4∼10.8)%-MnO slags was estimated to be 198 kJ/mol.

Original languageEnglish
Pages (from-to)63-70
Number of pages8
JournalISIJ International
Volume42
Issue number1
DOIs
Publication statusPublished - 2002 Jan 1

Fingerprint

Manganese oxide
Slags
Thermodynamic properties
Manganese
Steelmaking
Smelting
Carbon Monoxide
Silver
Partial pressure
Temperature
Ores
manganese oxide
Metals
Oxygen
Liquids

All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Jung, Sung Mo ; Rhee, Chang Hee ; Min, Dong Joon. / Thermodynamic properties of manganese oxide in BOF slags. In: ISIJ International. 2002 ; Vol. 42, No. 1. pp. 63-70.
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abstract = "It is necessary to understand the thermodynamic properties of MnO in steelmaking slags for the smelting reduction of Mn ore in BOF process. Studies of the manganese distribution between CaO-SiO2-FetO-MnO slags and liquid silver in equilibrium with solid Fe in the temperature range of 1 623 to 1 723 K were carried out under a CO/CO2 atmosphere. The FetO content in (32.4∼36.3){\%}CaO-(31.6∼44.0){\%}SiO2- (9.9∼24.1){\%}FeO-(0.4∼2.6){\%}Fe2O3-(8.9∼10.8){\%} MnO slags was found to have a linear relationship with oxygen partial pressure. The values of Fe3+/Fe2+ in the same slag system increase by increasing the FetO content. The Mn distribution ratio between slag and metal, ({\%}MnO)/[{\%}MN]Fe-Csat, increases with FeO content in a linear relationship over the measured FeO concentration range (6.7-24.1 mass{\%}). The Mn distribution ratio decreases with increasing CaF2, which is believed to have the effect of increasing the activities of MnO and FeO. Temperature dependence of equilibrium manganese distribution at pO2 = 6.6 × 10-12 atm in the temperature range of 1 623 to 1 723 K can be expressed as follows: log (MnO)/[{\%}Mn]Fe-Csat = 14 270/T - 6.55 The relative partial heat of solution of MnO into (32.7∼39.1) {\%}CaO-(32.7∼38.8){\%}SiO2-(10.2∼20.2∼20.78){\%}FeO- (1.0∼2.4){\%}Fe2O3-(9.4∼10.8){\%}-MnO slags was estimated to be 198 kJ/mol.",
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Thermodynamic properties of manganese oxide in BOF slags. / Jung, Sung Mo; Rhee, Chang Hee; Min, Dong Joon.

In: ISIJ International, Vol. 42, No. 1, 01.01.2002, p. 63-70.

Research output: Contribution to journalArticle

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N2 - It is necessary to understand the thermodynamic properties of MnO in steelmaking slags for the smelting reduction of Mn ore in BOF process. Studies of the manganese distribution between CaO-SiO2-FetO-MnO slags and liquid silver in equilibrium with solid Fe in the temperature range of 1 623 to 1 723 K were carried out under a CO/CO2 atmosphere. The FetO content in (32.4∼36.3)%CaO-(31.6∼44.0)%SiO2- (9.9∼24.1)%FeO-(0.4∼2.6)%Fe2O3-(8.9∼10.8)% MnO slags was found to have a linear relationship with oxygen partial pressure. The values of Fe3+/Fe2+ in the same slag system increase by increasing the FetO content. The Mn distribution ratio between slag and metal, (%MnO)/[%MN]Fe-Csat, increases with FeO content in a linear relationship over the measured FeO concentration range (6.7-24.1 mass%). The Mn distribution ratio decreases with increasing CaF2, which is believed to have the effect of increasing the activities of MnO and FeO. Temperature dependence of equilibrium manganese distribution at pO2 = 6.6 × 10-12 atm in the temperature range of 1 623 to 1 723 K can be expressed as follows: log (MnO)/[%Mn]Fe-Csat = 14 270/T - 6.55 The relative partial heat of solution of MnO into (32.7∼39.1) %CaO-(32.7∼38.8)%SiO2-(10.2∼20.2∼20.78)%FeO- (1.0∼2.4)%Fe2O3-(9.4∼10.8)%-MnO slags was estimated to be 198 kJ/mol.

AB - It is necessary to understand the thermodynamic properties of MnO in steelmaking slags for the smelting reduction of Mn ore in BOF process. Studies of the manganese distribution between CaO-SiO2-FetO-MnO slags and liquid silver in equilibrium with solid Fe in the temperature range of 1 623 to 1 723 K were carried out under a CO/CO2 atmosphere. The FetO content in (32.4∼36.3)%CaO-(31.6∼44.0)%SiO2- (9.9∼24.1)%FeO-(0.4∼2.6)%Fe2O3-(8.9∼10.8)% MnO slags was found to have a linear relationship with oxygen partial pressure. The values of Fe3+/Fe2+ in the same slag system increase by increasing the FetO content. The Mn distribution ratio between slag and metal, (%MnO)/[%MN]Fe-Csat, increases with FeO content in a linear relationship over the measured FeO concentration range (6.7-24.1 mass%). The Mn distribution ratio decreases with increasing CaF2, which is believed to have the effect of increasing the activities of MnO and FeO. Temperature dependence of equilibrium manganese distribution at pO2 = 6.6 × 10-12 atm in the temperature range of 1 623 to 1 723 K can be expressed as follows: log (MnO)/[%Mn]Fe-Csat = 14 270/T - 6.55 The relative partial heat of solution of MnO into (32.7∼39.1) %CaO-(32.7∼38.8)%SiO2-(10.2∼20.2∼20.78)%FeO- (1.0∼2.4)%Fe2O3-(9.4∼10.8)%-MnO slags was estimated to be 198 kJ/mol.

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