Thin film supercapacitor with ruthenium oxide electrode and solid electrolyte

Jae Hong Lim, Doo Jin Choi, Bong Hee Son, Sang Cheol Nam, Won I. Cho, Young Soo Yoon

Research output: Contribution to conferencePaper

Abstract

It is possible to fabricate all solid-state thin film supercapacitor (TFSC) with an amorphous LixPOyNz (LiPON), Ta 2O5 thin film electrolytes and ruthenium oxide film electrodes, which has the full cell structure of RuO2/LiPON/RuO 2/Pt, RuO2/Ta2O5/RuO2/Pt. The TFSC will be very useful to drive a microelectronic device if it can be hybrid with thin film battery (TFB). The ruthenium oxide thin films were grown on Pt/TiO2/SiO2/Si substrates by using direct current (d.c.) reactive magnetron sputtering at room temperature. Both LiPON and Ta 2O5 electrolyte films were grown on the RuO2 films by using radio frequency (r.f.) magnetron sputtering at room temperature. After the deposition of amorphous LiPON and Ta2O5 electrolyte films, RuO2 top electrode films were grown on the as-deposited electrolyte films by using d.c. reactive sputtering system. Room temperature charge-discharge measurements of the RuO2/LiPON/RuO 2/Pt TFSC at a constant current clearly revealed a typical supercapacitor behavior, even though the capacity of as-fabricated TFSC showed much lower than the bulk one and relatively fast decreased. However, room temperature charge-discharge curves of RuO2/Ta2O 5/RuO2 supercapacitor did not show the same pattern as above one. Electric double layer capacitance was prominent due to high dielectric constant of Ta2O5 material.

Original languageEnglish
Pages16-30
Number of pages15
Publication statusPublished - 2000 Dec 1
EventMicro Power Sources - Proceedings of the International Symposium - Toronto, Ont., Canada
Duration: 2000 May 142000 May 16

Other

OtherMicro Power Sources - Proceedings of the International Symposium
CountryCanada
CityToronto, Ont.
Period00/5/1400/5/16

Fingerprint

Solid electrolytes
Ruthenium
Thin films
Electrodes
Oxides
Electrolytes
Reactive sputtering
Magnetron sputtering
Oxide films
Temperature
Supercapacitor
Microelectronics
Permittivity
Capacitance
Substrates

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Lim, J. H., Choi, D. J., Son, B. H., Nam, S. C., Cho, W. I., & Yoon, Y. S. (2000). Thin film supercapacitor with ruthenium oxide electrode and solid electrolyte. 16-30. Paper presented at Micro Power Sources - Proceedings of the International Symposium, Toronto, Ont., Canada.
Lim, Jae Hong ; Choi, Doo Jin ; Son, Bong Hee ; Nam, Sang Cheol ; Cho, Won I. ; Yoon, Young Soo. / Thin film supercapacitor with ruthenium oxide electrode and solid electrolyte. Paper presented at Micro Power Sources - Proceedings of the International Symposium, Toronto, Ont., Canada.15 p.
@conference{b09846f3367342f09e0d4e4523f188ea,
title = "Thin film supercapacitor with ruthenium oxide electrode and solid electrolyte",
abstract = "It is possible to fabricate all solid-state thin film supercapacitor (TFSC) with an amorphous LixPOyNz (LiPON), Ta 2O5 thin film electrolytes and ruthenium oxide film electrodes, which has the full cell structure of RuO2/LiPON/RuO 2/Pt, RuO2/Ta2O5/RuO2/Pt. The TFSC will be very useful to drive a microelectronic device if it can be hybrid with thin film battery (TFB). The ruthenium oxide thin films were grown on Pt/TiO2/SiO2/Si substrates by using direct current (d.c.) reactive magnetron sputtering at room temperature. Both LiPON and Ta 2O5 electrolyte films were grown on the RuO2 films by using radio frequency (r.f.) magnetron sputtering at room temperature. After the deposition of amorphous LiPON and Ta2O5 electrolyte films, RuO2 top electrode films were grown on the as-deposited electrolyte films by using d.c. reactive sputtering system. Room temperature charge-discharge measurements of the RuO2/LiPON/RuO 2/Pt TFSC at a constant current clearly revealed a typical supercapacitor behavior, even though the capacity of as-fabricated TFSC showed much lower than the bulk one and relatively fast decreased. However, room temperature charge-discharge curves of RuO2/Ta2O 5/RuO2 supercapacitor did not show the same pattern as above one. Electric double layer capacitance was prominent due to high dielectric constant of Ta2O5 material.",
author = "Lim, {Jae Hong} and Choi, {Doo Jin} and Son, {Bong Hee} and Nam, {Sang Cheol} and Cho, {Won I.} and Yoon, {Young Soo}",
year = "2000",
month = "12",
day = "1",
language = "English",
pages = "16--30",
note = "Micro Power Sources - Proceedings of the International Symposium ; Conference date: 14-05-2000 Through 16-05-2000",

}

Lim, JH, Choi, DJ, Son, BH, Nam, SC, Cho, WI & Yoon, YS 2000, 'Thin film supercapacitor with ruthenium oxide electrode and solid electrolyte', Paper presented at Micro Power Sources - Proceedings of the International Symposium, Toronto, Ont., Canada, 00/5/14 - 00/5/16 pp. 16-30.

Thin film supercapacitor with ruthenium oxide electrode and solid electrolyte. / Lim, Jae Hong; Choi, Doo Jin; Son, Bong Hee; Nam, Sang Cheol; Cho, Won I.; Yoon, Young Soo.

2000. 16-30 Paper presented at Micro Power Sources - Proceedings of the International Symposium, Toronto, Ont., Canada.

Research output: Contribution to conferencePaper

TY - CONF

T1 - Thin film supercapacitor with ruthenium oxide electrode and solid electrolyte

AU - Lim, Jae Hong

AU - Choi, Doo Jin

AU - Son, Bong Hee

AU - Nam, Sang Cheol

AU - Cho, Won I.

AU - Yoon, Young Soo

PY - 2000/12/1

Y1 - 2000/12/1

N2 - It is possible to fabricate all solid-state thin film supercapacitor (TFSC) with an amorphous LixPOyNz (LiPON), Ta 2O5 thin film electrolytes and ruthenium oxide film electrodes, which has the full cell structure of RuO2/LiPON/RuO 2/Pt, RuO2/Ta2O5/RuO2/Pt. The TFSC will be very useful to drive a microelectronic device if it can be hybrid with thin film battery (TFB). The ruthenium oxide thin films were grown on Pt/TiO2/SiO2/Si substrates by using direct current (d.c.) reactive magnetron sputtering at room temperature. Both LiPON and Ta 2O5 electrolyte films were grown on the RuO2 films by using radio frequency (r.f.) magnetron sputtering at room temperature. After the deposition of amorphous LiPON and Ta2O5 electrolyte films, RuO2 top electrode films were grown on the as-deposited electrolyte films by using d.c. reactive sputtering system. Room temperature charge-discharge measurements of the RuO2/LiPON/RuO 2/Pt TFSC at a constant current clearly revealed a typical supercapacitor behavior, even though the capacity of as-fabricated TFSC showed much lower than the bulk one and relatively fast decreased. However, room temperature charge-discharge curves of RuO2/Ta2O 5/RuO2 supercapacitor did not show the same pattern as above one. Electric double layer capacitance was prominent due to high dielectric constant of Ta2O5 material.

AB - It is possible to fabricate all solid-state thin film supercapacitor (TFSC) with an amorphous LixPOyNz (LiPON), Ta 2O5 thin film electrolytes and ruthenium oxide film electrodes, which has the full cell structure of RuO2/LiPON/RuO 2/Pt, RuO2/Ta2O5/RuO2/Pt. The TFSC will be very useful to drive a microelectronic device if it can be hybrid with thin film battery (TFB). The ruthenium oxide thin films were grown on Pt/TiO2/SiO2/Si substrates by using direct current (d.c.) reactive magnetron sputtering at room temperature. Both LiPON and Ta 2O5 electrolyte films were grown on the RuO2 films by using radio frequency (r.f.) magnetron sputtering at room temperature. After the deposition of amorphous LiPON and Ta2O5 electrolyte films, RuO2 top electrode films were grown on the as-deposited electrolyte films by using d.c. reactive sputtering system. Room temperature charge-discharge measurements of the RuO2/LiPON/RuO 2/Pt TFSC at a constant current clearly revealed a typical supercapacitor behavior, even though the capacity of as-fabricated TFSC showed much lower than the bulk one and relatively fast decreased. However, room temperature charge-discharge curves of RuO2/Ta2O 5/RuO2 supercapacitor did not show the same pattern as above one. Electric double layer capacitance was prominent due to high dielectric constant of Ta2O5 material.

UR - http://www.scopus.com/inward/record.url?scp=5744228985&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=5744228985&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:5744228985

SP - 16

EP - 30

ER -

Lim JH, Choi DJ, Son BH, Nam SC, Cho WI, Yoon YS. Thin film supercapacitor with ruthenium oxide electrode and solid electrolyte. 2000. Paper presented at Micro Power Sources - Proceedings of the International Symposium, Toronto, Ont., Canada.