Three-Dimensional Flexible All-Organic Conductors for Multifunctional Wearable Applications

In Kyu Moon, Seonno Yoon, Hee Uk Lee, Seung Wook Kim, Jungwoo Oh

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

Wearable textile electrodes based on π-conjugated polymers are appealing alternatives to carbon fabrics, conductive yarns, or metal wires because of their design flexibility, low cost, flexibility, and high throughput. This provides the benefits of both electronics and textiles. Herein, a general and new method has been developed to produce tailorable, wearable energy devices that are based on three-dimensional (3D) poly(3,4-ethylenedioxythiophene) (PEDOT)-coated textile conductors. To obtain the desired electrode materials, both facile solution-dropping polymerization methods are used to fabricate a 3D flexible PEDOT conductor on a cotton textile (PEDOT/textile). PEDOT/textile shows a very low sheet resistance of 4.6-4.9 ω·sq-1. Here, we employ the example of this 3D network-like structure and the excellent electrical conductivities under the large deformation of PEDOT/textiles to show that wearable and portable heaters have immense potential. A flexible textile heater with a large area (8 × 7.8 cm2) reached a saturation temperature of ∼83.9 °C when a bias of 7 V was applied for ∼70 s due to the good electrical conductivity of PEDOT. To demonstrate the performance of all-solid-state supercapacitors, nano-ascidian-like PEDOT (PEDOT-NA) arrays were prepared via a simple vapor-phase polymerization of 3,4-ethylenedioxythiophene on PEDOT/textile to increase both the surface area and the number of ion diffusion paths. The PEDOT-NA arrays on PEDOT/textile showed outstanding performance with an areal capacitance of 563.3 mF·cm-2 at 0.4 mA·cm-2 and extraordinary mechanical flexibility. The maximum volumetric power density and energy density of the nanostructured PEDOT on the textile were 1.75 W·cm-3 and 0.0812 Wh·cm-3, respectively. It is expected that the wearable nanostructured conducting polymers will have advantages when used as structures for smart textronics and energy conversion/storage.

Original languageEnglish
Pages (from-to)40580-40592
Number of pages13
JournalACS Applied Materials and Interfaces
Volume9
Issue number46
DOIs
Publication statusPublished - 2017 Nov 22

Bibliographical note

Funding Information:
This work was supported by the Future Semiconductor Device Technology Development Program (10044735) funded by MOTIE (Ministry of Trade, Industry & Energy) and KSRC (Korea Semiconductor Research Consortium). It was also supported by the MSIP (Ministry of Scienceand ICT), Korea under the ICT Consilience Creative Program (IITP-2017-2017-0-01015) supervised by the IITP (Institute for Information & Communication Technology Promotion) and by the National Research Foundation (NRF) of Korea (Future Planning of Korea, MSIP No.2016R1D1A1A09918647) and Ministry of Trade, Industry & Energy of Korea (The Industrial Strategic Technology Development Program, 10051513).

Funding Information:
This work was supported by the Future Semiconductor Device Technology Development Program (10044735) funded by MOTIE (Ministry of Trade, Industry & Energy) and KSRC (Korea Semiconductor Research Consortium). It was also supported by the MSIP (Ministry of Science and ICT), Korea, under the “ICT Consilience Creative Program” (IITP-2017-2017-0-01015) supervised by the IITP (Institute for Information & Communication Technology Promotion) and by the National Research Foundation (NRF) of Korea (Future Planning of Korea, MSIP No. 2016R1D1A1A09918647) and Ministry of Trade, Industry & Energy of Korea (The Industrial Strategic Technology Development Program, 10051513).

Publisher Copyright:
© 2017 American Chemical Society.

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

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